The Laboratory of Environmental Chemistry and Advanced Materials
Prof. Ovadia Lev Research Group
Research
Lev group is interested in analytical chemistry and advanced materials. Examples of on going research projects include:
Analytical Chemistry
Electrochemical and mass spectrometric investigation of illicit drugs by mass spectrometry and/or by electroanalytical methods.
Development and implementation of analytical methods for the determination of traces of emerging organic contaminants and their use to quantify wastewater leakage to water sources.
Development of analytical sampling methods for the quantification of the chemical composition of pore water in the vadose zone.
Implementation of advanced and novel analytical methods for studies of the depth profile of DOC, oxygen, emerging pollutants and other parameters in the vadose zone of water recharge systems.
Advanced Materials
Stabilization of metal and semimetal oxide sols by a novel capping agent - hydrogen peroxide.
Coating of surfaces and particles by peroxy-nano particles.
Transformation of the peroxy-coatings to nanocrystalline oxides, or to the respective elements or sulfides by mild treatment.
Use of reduced graphene oxide-coated by p-block elements, their oxides in crystalline or amorphous forms as lithium ion battery and sodium ion battery anodes.
Development of nanostructured manganese oxide catalysts for water purification.
Ovadia Lev is a professor of chemistry at the Casali Center for Applied Chemistry, the Institute of Chemistry and head of Environmental Chemistry Laboratory of the Hebrew University of Jerusalem. His research focuses on water and wastewater treatment, development of advanced materials for environmental and green chemistry and the analytical chemistry and electrochemistry of trace organic contaminants.
Prof. Lev has contributed to the development of the fields of sol-gel electrochemistry and hydrogen peroxide sol-gel chemistry (including fundamental aspects and applications for lithium and sodium ion batteries), scanning electrochemical mass spectrometry (SCM) and scanning electrochemical microscopy (SECM). Professor Lev has been instrumental in providing science-based regulations, such as the Guidance manual for ozone disinfection in the USA, tools for quantification of leakage from Soil Aquifer Treatment systems to nearby drinking water wells, and quantification of wastewater leakage to water sources by quantification of emerging organic contaminants (micropollutants).
Prof. Lev is recipient of the Fulbright postdoctoral fellowship, the Barnard scholarship awarded by the AAAS and the USEPA, the Key Innovations Award awarded by the Hebrew University and he is Fellow of the International Society of Electrochemistry, the Rita Levi-Montalcini Award for scientific collaboration between Israel and Italy.
The group is participating in a collaborative project in Singapore, holds a laboratory in the CREATE campus in Singapore and some of its members are stationed in Singapore.
Paper statistics (Google Scholar): # of papers > 240; Citations > 12600; h-index 51.
Lakshmi V., Mikhaylov A. A., Medvedev A. G., Zhang C., Ramireddy T., Rahman M. M., Cizek P., Golberg D., Chen Y., Lev O., Prikhodchenko P. V., Glushenkov A. M. Enhanced thermal buffering of phase change materials by the intramicrocapsule sub per mille CNT dopant.Journal of Materials Chemistry A2020, 8, 11424-11434.
Mikhaylov A. A., Sladkevich S., Medvedev A. G., Prikhodchenko P. V., Gun J., Sakharov K. A., Xu Z. J., Kulish V., Nikolaev V. A., Lev O. Enhanced thermal buffering of phase change materials by the intramicrocapsule sub per mille CNT dopant.Applied Materials and Interfaces2020, 12, 16227-16235.
Mikhaylov A. A., Medvedev A. G., Grishanov D. A., Sladkevich S., Xu Z. J., Sakharov K. A., Meker S., Prikhodchenko P. V., Lev O. Hydrogen peroxide sol–gel coating of microencapsulated phase change materials by metal oxides.Journal of Sol-Gel Science and Technology2020, 95, 649-660.
Mikhaylov A. A., Medvedev A. G., Grishanov D. A., Edison E., Srinivasan M., Sladkevich S., Gun J., Prikhodchenko P. V., Lev O. Green synthesis of a nanocrystalline tin disulfide-reduced graphene oxide anode from ammonium peroxostannate: a highly stable sodium-ion battery anode.ACS Sustainable Chemistry & Engineering2020, 8, 5485-5494.
Churakov A. V., Grishanov D. A., Medvedev A. G., Mikhaylov A. A., Vener M. V., Navasardyan M. A., Tripol'skaya T. A., Lev O., Prikhodchenko P. V. Stabilization of hydrogen peroxide by hydrogen bonding in the crystal structure of 2-aminobenzimidazole perhydrate.CrystEngComm2020, 22, 2866-2872.
Chen R. R., Sun Y., Ong S. J. H., Xi S., Du Y., Liu C., Lev O., Xu Z. J. Antiferromagnetic inverse spinel oxide LiCoVO4 with spin-polarized channels for water oxidation.Advanced Materials2020, 32, 1907976.
Medvedev A. G., Grishanov D. A., Churakov A. V., Mikhaylov A. A., Lev O., Prikhodchenko P. V. Hydroperoxo double hydrogen bonding: stabilization of hydroperoxo complexes exemplified by triphenylsilicon and triphenylgermanium hydroperoxides.CrystEngComm2020, 22, 1922-1928.
Hitrik M., Lev O., Mandler D. Formation of asymmetric membrane by deposition of a hybrid sol-gel sublayer on top of a Langmuir film skin.Journal of Membrane Science2020, 595, 117559.
Pei M., Zhang B., He Y., Su J., Gin K., Lev O., Shen G., Hu S. State of the art of tertiary treatment technologies for controlling antibiotic resistance in wastewater treatment plants.Environment International2019, 131, 105026.
Zhang Y., Zhang B., He Y., Lev O., Yu G., Shen G., Hu S. DOM as an indicator of occurrence and risks of antibiotics in a city-river-reservoir system with multiple pollution sources.Science of the Total Environment2019, 686, 276-289.
Grishanov D. A., Churakov A. V., Medvedev A. G., Mikhaylov A. A., Lev O., Prikhodchenko P. V. Crystalline ammonium peroxogermanate as a waste-free, fully recyclable versatile precursor for germanium compounds.Inorganic Chemistry2019, 58, 1905-1911.
Shames A. I., Lev O., Mikhaylov A. A., Medvedev A. G., Gun J., Prikhodchenko P. V. Unusual stabilization of zinc peroxide by manganese oxide: mechanistic understanding by temperature-dependent EPR studies.The Journal of Physical Chemistry C2019, 123, 20884-20892.
Churakov A. V., Grishanov D. A., Medvedev A. G., Mikhaylov A. A., Tripol'skaya T. A., Vener M. V., Navasardyan M. A., Lev O., Prikhodchenko P. V. Cyclic dipeptide peroxosolvates: first direct evidence for hydrogen bonding between hydrogen peroxide and a peptide backbone.CrystEngComm2019, 21, 4961-4968.
Medvedev A. G., Mikhaylov A. A., Chernyshov I. Yu., Vener M. V., Lev O., Prikhodchenko P. V. Effect of aluminum vacancies on the H2O2 or H2O interaction with a gamma-AlOOH surface. A solid-state DFT study.Quantim Chemistry2019, 119, e25920.
Mikhaylov A. A., Medvedev A. G., Grishanov D. A., S. Sladkevich, Xu Z. J., Sakharov K. A., Prikhodchenko P. V., Lev O. Doubly coated, organic–inorganic paraffin phase change materials: zinc oxide coating of hermetically encapsulated paraffins.Advanced Materials and Interfaces2019, 6, 1900368.
Yasoda K. Y., Mikhaylov A. A., Medvedev A. G., Kumar M. S., Lev O., Prikhodchenko P. V., Batabyal S. K. Brush like polyaniline on vanadium oxide decorated reduced graphene oxide: Efficient electrode materials for supercapacitor.Journal of Energy Storage2019, 22, 188-193.
Yu L., Wang L. P., Liao H., Wang J., Feng Z., Lev O., Loo J. S. C., Sougrati M. T., Xu Z. J. Understanding fundamentals and reaction mechanisms of electrode materials for Na-ion batteries.Small2018, 14, 1703338.
Dvory N. Z., Livshitz Y., Kuznetsov M., Adar E., Gasser G., Pankratov I., Lev O., Yakirevich A. Caffeine vs. carbamazepine as indicators of wastewater pollution in a karst aquifer.Hydrology and Earth System Sciences2018, 22, 6371-6381.
Shvartsaman S., Lev O. Nonlinear dynamics in chemical reaction engineering: in celebration of Moshe Sheintuch's 70th birthday.Israel Journal of Chemistry2018, 58, 661-662.
Elkayam R., Aharoni A., Vaizel-Ohayon D., Sued O., Katz Y., Negev I., Marano R. B. M., Cytryn E., Shtrasler L., Lev O. Viral and microbial pathogens, indicator microorganisms, microbial source tracking indicators, and antibiotic resistance genes in a confined managed effluent recharge system.Journal of Environmental Engineering2018, 144, 05017011.
Mikhaylov A. A., Medvedev A. G., Grishanov D. A., Sladkevich S., Gun J., Prihodchenko P. V., Xu Z. J., Nagasubramanian A., Srinivasan M., Lev O. Vanadium oxide thin film formation on graphene oxide by microexplosive decomposition of ammonium peroxovanadate and its application as a sodium ion battery anode.Langmuir2018, 34, 2741-2747.
Grishanov D. A., Mikhaylov A. A., Medvedev A. G., Gun J., Nagasubramanian A., Srinivasan M., Lev O., Prihodchenko P. V. Synthesis of high volumetric capacity graphene oxide-supported tellurantimony Na- and Li-ion battery anodes by hydrogen peroxide sol gel processing.Journal of Colloid and Interface Science2018, 512, 165-171.
Grishanov D. A., Mikhaylov A. A., Medvedev A. G., Gun J., Prihodchenko P. V., Xu Z. J., Nagasubramanian A., Srinivasan M., Lev O. Graphene oxide-supported β-Tin telluride composite for Sodium- and Lithium-ion battery anodes.Energy Technology2018, 6, 127-133.
Sopilniak A., Elkayam R., Voloshenko-Rossin A., Lev O. Emerging organic pollutants in the vadose zone of a soil aquifer treatment system: Pore water extraction using positive displacement.Chemosphere2018, 190, 383-392.
Smolianitski-Fabian E., Cohen E., Dronova M., Voloshenko-Rossin A., Lev O. Discrimination between closely related synthetic cannabinoids by GC-Cold-EI-MS.Drug Testing and Analysis2018, 10, 474-487.
Dvory N. Z, Kuznetsov M., Livshitz Y., Gasser G., Pankratov I., Lev O., Adar E., Yakirevich A. Modeling sewage leakage and transport in carbonate aquifer using carbamazepine as an indicator.Water Research2018, 128, 157-170.
Muduli S. K., Varrla E., Kulkarni S. A., Han, G., Thirumal K., Lev O., Subodh M., Mathews N. 2D black phosphorous nanosheets as a hole transporting material in perovskite solar cells.Journal of Power Sources2017, 371, 156-161.
Rona M., Lev O., Gvirtzman H. Optimal remediation scheme for a wastewater recharge site: contaminants fate and transport model.Groundwater2017, 56, 871-880.
Grishanov D. A., Navasardyan M. A., Medvedev A. G., Lev O., Prihodchenko P. V., Churakov A. V. Hydrogen peroxide insular dodecameric and pentameric clusters in peroxosolvate structures.Angewandte Chemie2017, 56, 15241-15245.
Sopilniak A., Elkayam R., Lev O. Nitrification in a soil-aquifer treatment system: comparison of potential nitrification and concentration profiles in the vadose zone.Environmental Science: Processes and Impacts2017, 19, 1571-1582.
Voloshenko-Rossin A., Sladkevich S., Gasser G., Melman A., Lev O. Sensitive analysis of nitroguanidine in aqueous and soil matrices by LC-MS.Analytical Chemistry2017, 89, 9990-9996.
Mikhaylov A. A., Medvedev A. G., Tripol'skaya T. A., Popov V. S., Mokrushin A. S., Krut'ko D. P., Prihodchenko P. V., Lev O. H2O2 induced formation of graded composition sodium-doped tin dioxide and template-free synthesis of yolk–shell SnO2 particles and their sensing application.Dalton Transactions2017, 46, 16171-16179.
Sopilniak A., Elkayam R., Lev O. Quantification of dissolved organic matter in pore water of the vadose zone using a new ex-situ positive displacement extraction.Chemical Geology2017, 466, 263-273.
Lakshmi V., Chen Y., Mikhaylov A. A., Medvedev A. G., Sultana I., Rahman M. M., Lev O., Prikhodchenko P. V., Glushenkov A. M. Nanocrystalline SnS2 coated onto reduced graphene oxide: demonstrating the feasibility of a non-graphitic anode with sulfide chemistry for potassium-ion batteries.Chemical Communications2017, 53, 8272-8275.
Elkayam R., Kraitzer T., Popov V. S., Sladkevich S., Lev O. High performance of fixed-bed filtration for reagentless oxidative manganese removal.Journal of Environmental Engineering2017, 143, 04017030.
Medvedev A. G., Mikhaylov A. A., Grishanov D. A., Yu D. Y. W., Gun J., Sladkevich S., Lev O., Prikhodchenko P. V. GeO2 thin film deposition on graphene oxide by the hydrogen peroxide route: evaluation for lithium-ion battery anode.ACS Applied Materials and Interfaces2017, 9, 9152-9160.
Chernyshov Y. Y., Vener M. V., Prikhodchenko P. V., Medvedev A. G., Lev O., Churakov A. V. Peroxosolvates: formation criteria, H2O2 hydrogen bonding, and isomorphism with the corresponding hydrates.Grystal Growth and Design2017, 17, 214-220.
Zakon Y., Halicz L., Gelman F., Lev O. Compound-specific bromine isotope ratio analysis using gas chromatography/quadrupole
mass spectrometry.Rapid Communications in Mass Spectrometry2016, 30, 1951-1956.
Dronova M., Smolianitsky E., Lev O. Electrooxidation of new synthetic
cannabinoids: Voltammetric determination of drugs in seized street samples and artificial saliva.Analytical Chemistry2016, 88, 4487-4494.
Mikhaylov A. A., Medvedev A. G., Churakov A. V., Grishanov D. A., Prikhodchenko P. V., Lev O. Peroxide coordination
of Tellurium in aqueous solutions.Chemistry - A European Journal2016, 22, 2980-2986.
Jammer S., Gelman F., Lev O. Applicability of the Rayleigh equation for enantioselective metabolism of chiral
xenobiotics by microsomes, hepatocytes and in-vivo retention in rabbit tissues.Scientific Reports2016, 6, 23715.
Elkayam R., Sopilniak A., Gasser G., Pankratov I., Lev O. Oxidizer demand in the unsaturated zone of a
surface-spreading soil aquifer treatment system.Vadose Zone Journal2015, 14(11).
Elkayam R., Michail M., Mienis O., Kraitzer T., Tal N., Lev O. Soil aquifer treatment as disinfection unit.Journal of Environmental Engineering2015, 141(11), 05015001.
Ravenna Y., Xia L., Gun J., Mikhaylov A. A., Medvedev A. G., Lev O., Alfonta L. Biocomposite based on reduced graphene oxide film modified with phenothiazone and flavin adenine dinucleotide-dependent glucose dehydrogenase for glucose sensing and biofuel cell applications.Analytical Chemistry2015, 87, 9567-9571.
Medvedev A. G., Mikhaylov A. A., Churakov A. V., Vener M.V., Tripol'skaya T. A., Cohen S., Lev O., Prikhodchenko P. V. Potassium, Cesium, and ammonium peroxogermanates with inorganic hexanuclear peroxo bridged germanium anion isolated from aqueous solution. Inorganic Chemistry2015, 54, 8058-8065.
Jammer S., Rizkov D., Gelman F., Lev O. Quantitative structure-activity relationship correlation between molecular structure and the Rayleigh enantiomeric enrichment factor.Environmental Science: Processes and Impacts2015, 17, 1370-1376.
Gao J., Miao J., Li Y., Ganguly R., Zhao Y., Lev O., Liu B., Zhang Q. Dye-sensitized polyoxometalate for visible-light-driven photoelectrochemical cells.Dalton Transactions2015, 44, 14354-14358.
Yu D. Y. W., Batabyal S. K., Gun J., Sladkevich S., Mikhaylov A. A., Medvedev A. G., Novotortsev V. M., Lev O., Prikhodchenko P. V. Antimony and antimony oxide@graphene oxide obtained by the peroxide route as anodes for lithium-ion batteries.Main Group Metal Chemistry2015, 38, 43-50.
Mikhaylov A. A., Medvedev A. G., Mason C. W., Nagasubramanian A., Madhavi S., Batabyal S. K., Zhang Q., Gun J., Prikhodchenko P. V., Lev O. Graphene oxide supported sodium stannate lithium ion battery anodes by the peroxide route: low temperature and no waste processing.Journal of Materials Chemistry A2015, 3, 20681-20689.
Medvedev A. G., Shishkina A. V., Prikhodchenko P. V., Lev O., Vener M. V. The applicability of the dimeric heterosynthon concept to molecules with equivalent binding sites. A DFT study of crystalline urea-H2O2.RCS Advances2015, 5, 29601-29608.
Zentner E., Gerstl Z., Weisbrod N., Lev O., Pankratov I., Russo D., Gasser G., Voloshenko-Rosin A., Ronen D. Deep penetration of pharmaceuticals and personal care products through the vadose zone of effluent-irrigated land.Vadose Zone Journal2015, 14(1).
Voloshenko-Rossin A., Gasser G., Cohen K., Gun J., Cumbal-Flores L., Parra-Morales W., Sarabia F., Ojeda F., Lev O. Emerging pollutants in the Esmeraldas watershed in Ecuador: discharge and attenuation of emerging organic pollutants along the San Pedro-Guayllabamba-Esmeraldas rivers.Environmental Science: Processes and Impacts2015, 17, 41-53.
Wolanov Y., Shurki A., Prihodchenko P. V., Tripol'skaya T. A., Novotortsev V. M., Pedahzur R., Lev O. Aqueous
stability of alumina and silica perhydrate hydrogels: experiments and computations.Dalton Transactions2014, 43, 16614-16625.
Michman M., Appelbaum L., Gun J., Modestov A. D., Lev O. Homogeneous catalysis and selectivity in electrochemistry.Organometallics2014, 33, 4729-4737.
Hitrik M., Lev O., Mandler D. In situ electrodeposition of an asymmetric sol–gel membrane based on an octadecyltrimethoxysilane langmuir film.Chemistry - A European Journal2014, 20, 12104-12113.
Rona M., Gasser G., Negev I., Pankratov I., Lev O., Gvirtzman H. A 3-D hydrologic transport model of a water
recharge system using carbamazepine and chloride as tracers.Water Resources Research2014, 50, 4220-4241.
Gasser G., Pankratov I., Elhanany S., Glazman H., Lev O. Calculation of wastewater effluent
leakage to pristine water sources by the weighted average of multiple tracer approach.Water Resources Research2014, 50, 4269-4282.
Jammer S., Voloshenko A., Gelman F., Lev O. Chiral and isotope analyses for assessing the degradation of organic contaminants
in the environment: Rayleigh dependence.Environmental Science and Technology2014, 48, 3310-3318.
Prikhodchenko P. V., Yu D. Y. W., Batabyal S. K., Uvarov V., Gun J., Sladkevich S., Mikhaylov A. A., Medvedev A. G., Lev O. Nanocrystalline tin disulfide coating of reduced graphene oxide produced by the peroxostannate deposition route for sodium ion battery anodes.Journal of Materials Chemistry A2014, 2, 8431-8437.
Yu D. Y. W., Prikhodchenko P. V., Mason C. W., Batabyal S. K., Gun J., Sladkevich S., Medvedev A. G., Lev O. High-capacity antimony sulphide nanoparticle-decorated graphene composite as anode for sodium-ion batteries.Nature Communications2013, 4, 2922.
Voloshenko A., Tan K. J., Kloc C., Lev O., Shelkov R., Sladkevich S., Prikhodchenko P. V., Gun J. Mass
spectrometric analysis of impurities in crystalline organic semiconductors.Organic Electronics2013, 14, 378-388.
Wolanov Y., Prikhodchenko P. V., Medvedev A. G., Pedahzur R., Lev O. Zinc dioxide nanoparticulates: a hydrogen peroxide source at moderate pH.Environmental Science and Technology2013, 47, 8769-8774.
Harel M., Weiss G., Lieman-Hurwitz J., Gun J., Lev O., Lebendiker M., Temper V., Block C., Sukenik A., Zohary T., Braun S., Carmeli S., Kaplan A. Interactions between Scenedesmus and Microcystis may be used to clarify the role of secondary metabolites.Environmental Microbiology Reports2013, 5, 97-104.
Prikhodchenko P. V., Gun J., Sladkevich S., Mikhaylov A. A., Lev O., Tay Y. Y., Batabyal S. K., Yu D. Y. W. Conversion of hydroperoxoantimonate coated graphenes to Sb2S3@graphene for a superior lithium battery anode.Chemistry of Materials2012, 24, 4750-4757.
Bahartan K., Gun J., Sladkevich S., Prikhodchenko P. V., Lev O., Alfonta L. Encapsulation of yeast displaying glucose oxidase on their surface in graphene oxide hydrogel scaffolding and
its bioactivation.Chemical Communications2012, 48, 11957-11959.
Sladkevich S., Gun J., Prikhodchenko P. V., Gutkin V., Mikhaylov A. A., Novotortsev V. M., Zhu J. X., Yang D., Hng H. H., Tay Y. Y., Tsakadze Z., Lev O. Peroxide induced tin oxide coating of graphene oxide at room temperature and its application for lithium ion batteries.Nanotechnology2012, 23, 485601.
Sladkevich S., Gun J., Prikhodchenko P. V., Gutkin V., Mikhaylov A. A., Medvedev A. G., Tripol'skaya T. A., Lev O. The formation of a peroxoantimonate thin film coating on graphene oxide (GO) and the influence of the GO on its transformation to antimony oxides and elemental antimony.Carbon2012, 50, 5463-5471.
Gun J., Kulkarni S. A., Xiu W., Batabyal S. K., Sladkevich S., Prikhodchenko P. V., Gutkin V., Lev O. Graphene oxide organogel electrolyte for quasi solid dye sensitized solar cells.Electrochemistry Communications2012, 19, 108-110.
Gasser G., Pankratov I., Elhanany S., Werner P., Gun J., Gelman F., Lev O. Field and laboratory studies
of the fate and enantiomeric enrichment of venlafaxine and O-desmethylvenlafaxine under aerobic and anaerobic conditions.Chemosphere2012, 88, 98-105.
Medvedev A. G., Mikhaylov A. A., Churakov A.V., Prikhodchenko P. V., Lev O. Ammonium and caesium carbonate peroxosolvates: supramolecular networks formed by hydrogen bonds.Acta Crystallographica: Section C2012, 68, i20-i24.
Recent patents
Yu Y. W. D., Batabyal S. K., Lev O., Gun J., Prikhodchenko P. V. US9755227Method for forming a reduced graphene oxide/metal sulfide composite and its use as an anode for batteries.granted 2017.
Lev O., Sladkevich S., Prikhodchenko P. V., Gun G. US20140044922Process for the formation of metal oxide nanoparticles coating of a solid substrate.granted 2018.
Alfonta L., Ravenna Y. D., Lev O., Gun J. US20170173036Phenothiazine/phenothiazine – graphene oxide composite.filed: July 21, 2015; publication: June 22, 2017.