Personal Details of Israeli Investigator: Jochanan Blum

 

Name:                                   Jochanan Blum                  

Employment Status:           Professor of Chemistry

Date of Birth:                      04.09.1933

Nationality:                         Israeli

Institution:                           Hebrew University, Institute of Chemistry

Office Address:                   Hebrew University, Jerusalem 91904, Israel

Tel. at the Institution:        +972-2-6585329

Fax:                                                   +972-2-6513832

E-mail:                                  jblum@chem.ch.huji.ac.il

Private (home) address:     13 Hameshoreret Street, Jerusalem 96348, Israel

 

Educational Background

From Year

To Year

Institution

Specialization

Degree

1953

1958

Hebrew University

Chemistry and Physics

M.Sc.

1958

1961

Hebrew University

Organic Chemistry

Ph.D.

 

 

 

 

 

Employment History

From Year

To Year

Institution

Area of research

 

Title

 

1978

present

Hebrew University

Organic & organometallic chemistry; homogeneous and heterogeneous catalysis

Professor

1972

1978

Hebrew University

Cancer research & catalysis

Assoc. Professor

1972

1973

Univ. of Chicago

Homogeneous catalysts

Visit. Assoc.

1968

1972

Hebrew University

Homogeneous catalysis; cancer research

Sen. Lecturer

1964

1968

Hebrew University

Cancer research

Lecturer

1962

1964

Ohio State Univ.

Cancer research

Res. Associate

1960

1962

Hebrew University

Cancer research

Assistant

 

Major Research Interests

Application of organometallic chemistry to organic synthesis; hydrogen transfer reactions and coupling processes; mixed-metal catalysts; catalyses by doped sol-gel glasses; one-pot multi-step processes; new methodology for conducting organic catalyses in aqueous media (370 publications).

 

 

 

 

 

 


 

JOCHANAN BLUM

LIST OF PUBLICATIONS

 

(articles and abstracts)

 

1)         A Quick and Direct Micro-Heterometric Determination of Traces of Copper with Rubeanic Acid in Metals and Alloys. M. Bobtelsky and J. Blum, Anal. Chim. Acta, 15, 62-72 (1956).

 

2)         p-Vinylbenzoic Acid and p-Vinylphenylacetic Acid. E.D. Bergmann and J. Blum, Bull. Res. Counc. of Israel, 7A, 93 (1958).

 

3)         Fluoro-Derivatives of Polycyclic Carcinogenic Compounds. E.D. Bergmann, J. Blum, S. Butanaro and A. Heller, Tetrahedron Lett., 15-18 (1959).

 

4)         p-Vinylbenzoic and p-Vinylphenylacetic Acids. E.D. Bergmann and J. Blum, J. Org. Chem., 24, 549-551 (1959).

 

5)         Fluorine Substituted Aromatic Polycyclic Hydrocarbons in Biologically Active Regions. J. Blum, Ph.D. Thesis, The Hebrew University, Jerusalem, 1960 pp. 140.

 

6)         Dehalogenation in the Elbs Reaction. E.D. Bergmann and J. Blum, J. Org. Chem., 25, 474-475 (1960).

 

7)         Fluorine Containing Polycyclic Compounds of the Carcinogenic Series. E.D. Bergmann and J. Blum, Bull. Res. Counc. of Israel, 9A, 85-86 (1960).

 

8)         An Unusual Halogen Exchange Reaction. E.D. Bergmann, J. Blum and S. Butanaro, J. Org. Chem., 26, 3211-3214 (1961).

 

9)         Further Observations on the Elbs Reaction. E.D. Bergmann and J. Blum, J. Org. Chem., 26, 3214-3216 (1961).

 

10)       Fluorine-Substituted 1,2-Benzanthracene and 3,4-Benzophenanthrene Derivatives and Related Compounds. E.D. Bergmann and J. Blum, J. Org. Chem., 27, 527-533 (1962).

 

11)       The Reduction of 1- and 2-Chloroanthraquinones. E. Kariv and J. Blum, Bull. Res. Counc. of Israel, 11A, 26-27 (1962).

 

12)       Carcinogenic Activity of Some Fluorinated Polycyclics. E.D. Bergmann, J. Blum and A. Haddow, Nature, 200, 480 (1963).

 

13)       The Synthesis and Ionization Constants of the Six Hydroxybenzo[c]-phenanthrenes. M.S. Newman and J. Blum, J. Am. Chem. Soc., 86, 503-507 (1964).

 

14)       The Synthesis and Ionization Constants of the Six Aminobenzo[c]-phenanthrenes. M.S. Newman and J. Blum, J. Am. Chem. Soc., 86, 1835-1839  (1964).

 

15)       Molecular Compounds of 4-Bromo- and 4-Iodo-2,5,7-trinitrofluorenone. M.S. Newman and J. Blum, Isr. J. Chem., 2, 301 (1964).

 

 

16)       4-Bromo- and 4-Iodo-2,5,7-trinitrofluorenones as Complexing Agents. M.S. Newman and J. Blum, J. Am. Chem. Soc., 86, 5600-5602 (1964).

 

17)       Two Cases of Unexpected Formation of the Fluoranthene System. E.D. Bergmann, P. Bracha, J. Blum and M. Engelrath, J. Org. Chem., 29, 3092-3093 (1964).

 

18)       Fluorine-Substituted Carcinogenic Hydrocarbons. J. Blum, Isr. J. Chem., 3, 59p-60p (1965).

 

19)       The Synthesis of 1-, 2-, 3- and 4-Chloroanthrone. E.D. Bergmann, J. Blum and E. Kariv, Isr. J. Chem., 3, 91-100 (1965).

 

20)       Novel Decarbonylation, Desulfonylation and Desazotization Reactions Catalyzed by Rhodium Complexes. J. Blum, Isr. J. Chem., 4, 15p-16p (1966).

 

21)       The Introduction of Chlorine and Bromine into Aromatic Polycyclics by a Novel Method. J. Blum and E. Oppenheimer, Isr. J. Chem., 4, 18p (1966).

 

22)       The Decarbonylation of Aroyl to Aryl Chlorides. J. Blum, Tetrahedron Lett., 1605-1608 (1966).

 

23)       Desulfonylation of Aromatic Sulfonyl Chlorides. A New Synthesis of Aryl Chlorides. J. Blum, Tetrahedron Lett., 3041-3045 (1966).

 

24)       The Synthesis of 5-Fluorodibenz[a,h]anthracene. J. Blum and E.D. Bergmann, J. Org. Chem., 32, 342-344 (1967).

 

25)       The Syntheses of 4-Fluorobenzo[a]pyrene and 8-Fluorobenz[l]aceanthrylene. J. Blum and E.D. Bergmann, J. Org. Chem., 32, 344-346 (1967).

 

26)       Decarbonylation of Aromatic Carbonyl Compounds Catalyzed by Rhodium Complexes. J. Blum, E. Oppenheimer and E.D. Bergmann, J. Am. Chem. Soc., 89, 2338-2341 (1967).

 

27)       Homogeneous Oxidation Using Ruthenium and Rhodium Complexes. J. Blum, and H. Rosenman, Isr. J. Chem., 5, 69p (1967).

 

28)       Oxidation of Alkylbenzenes, Catalyzed by Chlorotris(triphenylphosphine)rhodium. J. Blum, H. Rosenman and E.D. Bergmann, Tetrahedron Lett., 3665-3668 (1967).

 

29)       The Catalytic Decarbonylation of Aroyl to Aryl Iodides. J. Blum, H. Rosenman and E.D. Bergmann, J. Org. Chem., 33, 1928-1930 (1968).

 

30)       Decarbonylation of Aromatic Anhydrides Catalyzed by Rhodium Complexes. J. Blum and Z. Lipshes, Proc. 11th Internat. Conference Coordin. Chem., Haifa, Sept. 1968. Paper A 17 (pp. 48-50).

 

31)       Dehydrogenation, Decarbonylation and Desulfonylation Reactions Catalyzed by Platinum-Metal Complexes. J. Blum, Sh. Biger, D. Milstein, Y. Sasson and G. Scharf, Isr. J. Chem., 7, 22p (1969).

 

32)       Catalytic Isomerization of Allylbenzene and Phenylbutenes by Some Ru, Rh and Ir Complexes. J. Blum and Y. Pickholtz, Isr. J. Chem., 7, 23p (1969).

           

33)       The Synthesis of 12-Fluoro-7-methyl- and 7-Fluorobenz[a]anthracene. J. Blum, F. Grauer and E.D. Bergmann, Tetrahedron, 25, 3501-3507 (1969).

 

34)       Homogeneous Benzylic Oxidation Catalyzed by Some Complexes of the Platinum Group. J. Blum, J.Y. Becker, H. Rosenman and E.D. Bergmann, J. Chem. Soc., Sect. B, 1000-1004 (1969).

 

35)       Catalytic Conversion of Benzoic Anhydrides into Fluorenones. J. Blum and Z. Lipshes, J. Org. Chem., 34, 3076-3080 (1969).

 

36)       Homogeneous Catalytic Isomerization of Allylbenzene and Phenylbutenes by Some Platinum-Metal Complexes. J. Blum and Y. Pickholtz, Israel J. Chem., 7, 723-733 (1969).

 

37)       Desulfonylation of Aromatic Sulfonyl Halides Catalyzed by Some Platinum-Metal Complexes. J. Blum and G. Scharf, J. Org. Chem., 35, 1895-1899 (1970).

 

38)       Isomerization of 1,4-Diarylbutenes by Complexes of the Platinum Group. J. Blum and Y. Becker, Isr. J. Chem., 8, 2p (1970).

 

39)       Homogeneous Dehydrogenation Reactions Catalyzed by Complexes of the Platinum Group. J. Blum and S. Biger, Tetrahedron Lett., 1825-1828 (1970).

 

40)       A Novel Synthesis of Nitriles from Secondary Amides. J. Blum and A. Fisher, Tetrahedron Lett., 1963-1966 (1970).

 

41)       The Decarbonylation/Dehydrohalogenation Reaction of Acyl Halides by Iridium Complexes. J. Blum and S. Kraus, Isr. J. Chem., 8, 3p (1970).

 

42)       Further Observations on the Catalytic Transformation of Benzoic Anhydrides into Fluorenones and Biphenyls. J. Blum, D. Milstein and Y. Sasson, J. Org. Chem., 35, 3233-3237 (1970).

 

43)       Neutral Organometallic Complexes as Defined Intermediates in Some New Catalytic Reactions. E.D. Bergmann and J. Blum, Plenary Lecture, 21st Annual Meeting, Societe de Chimie Physique, Paris Sept. 1970, pp. 125-135.

 

44)       Homogeneous Catalytic Transfer-Hydrogenation of a,b-Unsaturated Carbonyl Compounds by Dichlorotris(triphenylphosphine)ruthenium. Y. Sasson and J. Blum, Tetrahedron Lett., 2167-2170 (1971).

 

45)       Decarbonylation and Dehydrohalogenation of Aliphatic Acyl Halides by Iridium and Rhodium Complexes. J. Blum, S. Kraus and Y. Pickholtz, J. Organomet. Chem., 33, 227-240 (1971).

 

46)       Homogeneous Catalytic Isomerization and Disproportionation of Cyclic Terpenes by Some Complexes of the Platinum Metals. J. Blum and Y. Pickholtz, Proc. 41st Annual Meeting Isr. Chem. Soc., 216 (1971).

 

47)       Photocyclization of Substituted 1,4-Distyrylbenzenes to Dibenz[a,h]-anthracenes. J. Blum and M. Zimmerman, Tetrahedron 28, 275-280 (1972).

 

 

48)       Hydrogen Transfer from Formyl Compounds to a,b-Unsaturated Ketones Catalyzed by Ru, Rh and Ir Complexes. J. Blum, Y. Sasson and S. Iflah, Tetrahedron Lett., 1015-1918 (1972).

 

49)       A Method for Increasing the Oxidizing Effectiveness of 30% Hydrogen  Peroxide. J. Blum, Y. Pickholtz and H. Hart, Synthesis, 195 (1972).

 

50)       The Isomerization of 1,4-Diarylbutenes by Ruthenium-Phosphine Complexes. J. Blum and Y. Becker, J. Chem. Soc., Perkin 2 Trans., 982-989 (1972).

 

51)       The Mechanism of Catalytic Hydrogen Transfer from Carbinols to  a,b-Unsaturated Carbonyl Compounds. Y. Sasson and J. Blum, Proc. 42nd Annual Meeting Isr. Chem. Soc., Dec. 1972, p. 39.

 

52)       The Catalytic Decomposition of Secondary Carboxamides by Transition-Metal Complexes. J. Blum, A. Fisher and E. Greener, Tetrahedron, 29, 1073-1081 (1973).

 

53)       Hydrogen Transfer Reactions: Ethylene Glycol as a Hydrogenating Agent for Chalcones. Y. Sasson, M. Cohen and J. Blum, Synthesis, 359-360 (1973).

 

54)       RuCl2(PPh3)3-Catalyzed Transfer Hydrogenation of Cyclohexane-1,3-diones. J. Sasson, J. Blum and E. Dunkelblum, Tetrahedron Lett., 3199-3202 (1973).

 

55)       Effect of a Ru(II) Catalyst on the Rate of Equilibration of Carbinols  and Ketones. Y. Sasson, P. Albin and J. Blum, Tetrahedron Lett.,  833-836 (1974).

 

56)       Reactions of RuCl2(PPh3)3 with Carbinols: Formation of Ethers, Hydrogen-Deuterium Exchange and Racemisation of Optically Active Alcohols. Y. Sasson and J. Blum, J.C.S. Chem. Commun., 309-310 (1974).

 

57)       A Simple, One Step Synthesis of Benzo- and Dibenzofluorenones. J. Blum, M. Ashkenasy and Y. Pickholtz, Synthesis, 352-353 (1974).

 

58)       Homogeneous Isoaromatization of Alicyclic Dienones Catalyzed by Complexes of the Platinum Group. Y. Pickholtz, Y. Sasson and J. Blum, Tetrahedron Lett., 1263-1266 (1974).

 

59)       Homogeneous Catalytic Transformation of Aryl-Substituted Epoxides by Some Complexes of the Platinum Metals. D. Milstein, O. Buchman and J. Blum, Tetrahedron Lett., 2257-2260 (1974).

 

60)       A Simple Route From Dicyclopentadiene to Trishomocubanone. J. Blum, Ch. Zlotogorski and A. Zoran, Tetrahedron Lett., 1117-1120 (1975).

 

61)       Dichlorotris(triphenylphosphine)ruthenium-Catalyzed Hydrogen Transfer from Alcohols to Saturated and a,b-Unsaturated Ketones. Y. Sasson and J. Blum, J. Org. Chem., 40, 1887-1896 (1975).

 

62)       A Simple RuCl2(PPh3)3-Catalyzed Synthesis of the 3,5,6,7-Tetrahydro-4(2H)-benzofuranone System. P. Albin, J. Blum, E. Dunkelblum and Y. Sasson, J. Org. Chem., 40, 2402-2403 (1975).

 

63)       A Novel Conversion of Epoxides to Esters by Ru and Rh Complexes. J. Blum, B. Zinger, O. Buchman and D. Milstein, Proc. 25th IUPAC Congress, Jerusalem, July 1975, p. 63.

 

64)       A New Approach to the Carcinogenicity of Aromatic Polycyclic Hydrocarbons. Preparation of Arene Imines and Disubstituted Arene Oxides. J.  Blum, D. Avnir, Y. Ittah and I. Shahak, Proc. 43rd Annual Meeting Isr. Chem. Soc., Oct. 1975, p. 13.

 

65)       Rhodium- and Silver-Catalyzed Rearrangement of Bicyclo[2.2.0]hexane and Tricyclo-[4.2.0.02,5]octane. J. Halpern, M. Sohn and J. Blum, Proc. 43rd Annual Meeting Isr. Chem. Soc., Oct. 1975, p. 22.

 

66)       Disubstituted "K-Region" Arene Oxides. D. Avnir, A. Grauer, D. Dinur and J. Blum, Tetrahedron, 31, 2457-2459 (1975).

 

67)       Polycyclic Arene Imines. J. Blum, Y. Ittah and I. Shahak, Tetrahedron Lett., 4607-4610 (1975).

 

68)       Extrusion of Halogen Atoms from Aromatic Compounds by Transition Metal Complexes. Reaction of IrCl(CO)(PPh3)2 with Halogenated Benzaldehydes. J. Blum, Z. Aizenshtat and Sh. Iflah, Transition Met. Chem., 1, 52-54 (1976).

 

69)       A Heterocyclic Arene Oxide: 5,6-Diphenylbenz[c]acridine 5,6-Oxide. D. Avnir and J. Blum, J. Heterocyclic Chem., 13, 619-621 (1976).

 

70)       Oxidative Addition of Aryl Halides to Iridium(I) Complexes. A New Arylation Reagent. J. Blum, M. Weitzberg and R.J. Mureinik, J. Organomet. Chem., 122, 261-264 (1976).

 

71)       A New One-Step Synthesis of Aziridines from Oxiranes. I. Shahak, Y. Ittah and J. Blum, Tetrahedron Lett., 4003-4004 (1976).

 

72)       Homogeneous Transition Metal Catalyzed Hydrogen Transfer in Carbinols. J. Blum, I. Pri-Bar and O. Buchman, Proc. 44th Annual Meeting Isr. Chem. Soc., June 1977, OR-15.

 

73)       Stable Polycyclic Arene Imines. J. Blum, Y. Ittah and I. Shahak, Proc. 44th Annual Meeting Isr. Chem. Soc., June 1977, OR-7.

 

74)       Reductive Coupling of Benzhydrols by Homogeneous Ruthenium Catalysts. I. Pri-Bar, O. Buchman and J. Blum, Tetrahedron Lett., 1443-1446 (1977).

 

75)       Selective Transformation of vic-Disubstituted Epoxides into Ketones by Homogeneous Transition Metal Catalysts. D. Milstein, O. Buchman and J. Blum, J. Org. Chem., 42, 2299-2308 (1977).

 

76)       Chlorocarbonylbis(triphenylphosphine)iridium-Catalyzed Isomerization,  Isoaromatization and Disproportionation of Some Cycloalkanones Having Exocyclic Double Bonds. Z. Aizenshtat, M. Hausmann, Y. Pickholtz, D. Tal and J. Blum, J. Org. Chem., 42, 2386-2394 (1977).

 

77)       Mass Spectrometric Fragmentation of Some Arylidenecycloalkanones. Z. Aizenshtat, M. Hausmann, Y. Pickholtz, D. Tal and J. Blum, J. Org. Chem., 42, 2394-2398 (1977).

 

 

78)       An Unusual Diels-Alder Reaction of 2-Vinylnaphthalene with Benzyne. Y. Ittah, I. Shahak, J. Blum and J. Klein, Synthesis, 678-679 (1977).

 

79)       Selective Hydrogen Transfer Reactions in Carbinols, Ketones and Oxiranes by Transition Metal Catalysts. J. Blum, J. Mol. Catal., 3, 33-37 (1977).

 

80)       Stable Arene Imines. Y. Ittah, I. Shahak, and J. Blum, J. Org. Chem., 43, 397-402 (1978).

 

81)       A Mechanistic Study of the Oxidative Addition of Aryl Iodides to Iridium(I) Complexes. R.J. Mureinik, M. Weitzberg and J. Blum, Proc. 45th Annual Meeting, Isr. Chem. Soc., June, 1978, I-11.

 

82)       Isomerization of Allyl Alcohols in a Two-Liquid Phase System Using a Water Soluble Ruthenium Catalyst. Y. Sasson, A. Zoran and J. Blum, Proc. 45th Annual Meeting, Isr. Chem. Soc., June, 1978, OR-27.

 

83)       Homogeneous Ru(II)-Catalyzed Hydrogenolysis of Trihalomethyl Compounds in Presence of Alcohols. Y. Sasson, P. Albin and J. Blum, Proc. 45th Annual Meeting, Isr. Chem. Soc., June 1978, OR-28.

 

84)       Dimerization of Terminal Epoxides by Homogeneous Transition Metal Catalysts. A Novel Synthesis of Carboxylic Esters. J. Blum, B. Zinger, D. Milstein and O. Buchman, J. Org. Chem., 43, 2961-2967 (1978).

 

85)       Isolation of a Metalocyclic Intermediate in [Ir(CO)3Cl]2-Catalyzed Rearrangement of 1,3-Bishomocubane. J. Blum, Ch. Zlotogorski, H. Schwarz and C. Hohne, Tetrahedron Lett., 3501-3504 (1978).

 

86)       A New Aziridine Synthesis from 2-Azido Alcohols and Tertiary Phosphines. Preparation of Phenanthrene 9,10-Imine. Y. Ittah, Y. Sasson, I. Shahak, S. Tsaroom and J. Blum, J. Org. Chem., 43, 4271-4273 (1978).

 

87)       Mutagenicity of Phenanthrene and Phenanthrene K-Region Derivatives. M. Bucker, H.R. Glatt, K.L. Platt, D. Avnir, Y. Ittah, J. Blum and F. Oesch, Mutation Res., 66, 337-348 (1979).

 

88)       Rhodium(I)-Catalyzed Rearrangements of Strained Molecules Containing Fused Cyclobutane Rings. M. Sohn, J. Blum and J. Halpern, J. Am. Chem. Soc., 101, 2694-2698 (1979).

 

89)       Kinetics and Mechanism of Oxidative Addition of Aryl Iodides to Iridium(I) Complexes. R.J. Mureinik, M. Weitzberg and J. Blum, Inorg. Chem., 18, 915-918 (1979).

 

90)       Thermal Transformation of Halo-Tris(triphenylphosphine)rhodium(I) Complexes into Biaryls. M. Lewin, Z. Aizenshtat and J. Blum, Proc. 46th Annual Meeting Isr. Chem. Soc., June 1979, OC-12.

 

91)       Isomerization of Allyl Compounds by Supported Rh(I), Ir(I) and Ru(II) Catalysts. A. Zoran, Y. Sasson and J. Blum, Proc. 46th Annual Meeting,  Isr. Chem. Soc., June 1979, OC-15.

 

92)       Isomerization of Allyl Alcohols by a Water Soluble Ruthenium Catalyst in a Two Liquid Phase System. Y. Sasson, A. Zoran and J. Blum, J. Mol. Catal., 6, 289-292 (1979).

93)       Double Bond Isomerization by Polymer-Attached Rh(I), Ir(I) and Ru(II) Catalysts. A. Zoran, Y. Sasson and J. Blum, Proc. 9th Internat. Conference Organometal. Chem., Dijon, Sept. 1979, C-25.

 

94)       "K-Region" Imines of Some Carcinogenic Aromatic Hydrocarbons. J. Blum, I. Yona, S. Tsaroom and Y. Sasson, J. Org. Chem., 44, 4178-4182 (1979).

 

95)       Homogeneous and Heterogeneous Hydrogen Transfer in Carbinols by Group VIII Catalysts. J. Blum, I. Pri-Bar and O. Buchman, "Catalysis in Chemistry and Biochemistry. Theory and Experiment" (B. Pullman ed.), Riedel Pub. Co., Dordrecht-Holland, 1979, pp. 265-272.

 

96)       Formation of Diaryls by Thermal Decomposition of Rhodium(I) Triarylphosphine Complexes. M. Lewin, Z. Aizenshtat and J. Blum, J. Organomet. Chem., 184, 255-261 (1980).

 

97)       Photochemistry of 9,10-Diphenylphenanthrene 9,10-Oxide. A Photopinacol Rearrangement and an Unusual Case of Triplet Derived Oxepin. D. Avnir and J. Blum, Proc. 47th Annual Meeting, Isr. Chem. Soc., Sept. 1980, p. 23.

 

98)       Photochemistry of Phenanthrene 9,10-Imine. M. Weitzberg, Z. Aizenshtat and J. Blum, Proc. 47th Annual Meeting, Isr. Chem. Soc., Sept. 1980, p. 27.

 

99)       An Improved Synthesis of Carbocyclic and Heterocyclic Arene Imines. M. Weitzberg, Z. Aizenshtat, P. Jerushalmy and J. Blum, J. Org. Chem., 45, 252-4254 (1980).

 

100)     Synthesis and Photopinacol Rearrangement of 1a,9b-Dihydro-1a,9b-diphenylphenanthro-[9,10-b]oxirene. D. Avnir and J. Blum, J. Heterocyclic Chem., 17, 1349-1350 (1980).

 

101)     Transformation of Carbinols by RuCl2(PPh3)3 and by Some Other Transition Metal Catalysts. I. Pri-Bar, O. Buchman, H. Schumann, H.J Kroth and J. Blum, J. Org. Chem., 45, 4418-4428 (1980).

 

102)     A General Synthesis of Unsubstituted Arene Imines. 3-Methylcholanthrene 11,12-Imine. I. Yona and J. Blum, Org. Prep. Proc. Int., 13, 109-112 (1981).

 

103)     Catalytic Double Bond Isomerization by Polystyrene-Anchored RuCl2(PPh3)3. A. Zoran, Y. Sasson and J. Blum, J. Org. Chem., 46,  255-260 (1981).

 

104)     Reversible Ion Pair Extraction in a Biphasic System. Application in RhCl3-Catalyzed Isomerization of Allylic Compounds. Y. Sasson, A. Zoran  and J. Blum, J. Mol. Catal., 11, 293-300 (1981).

 

105)     Selective Hydrogen Transfer from Formic Acid to a,b-Unsaturated Ketones by Polystyrene-Bound IrCl(CO)(PPh3)2. J. Azran, O. Buchman and J. Blum, Tetrahedron Lett., 22, 1925-1928 (1981).

 

106)     Reactions of Unsubstituted and N-Substituted Phenanthrene 9,10-Imine. J. Blum, M. Weitzberg and Z. Aizenshtat, Proc. 8th Internat. Congr. Heterocyclic Chem., Graz, Aug. 1981, p. 70.

 

 

107)     Catalytic Activity of Supported Ir(I) in Hydrogen Transfer from Formic Acid to Unsaturated Carbon-Carbon Bonds. J. Azran, O. Buchman and J. Blum, Proc. 48th Annual Meeting Isr. Chem. Soc., Oct. 1981, p. 37.

 

108)     Synthesis of Bisimines of Pyrene and Dibenz[a,h]anthracene. I. Yona and J. Blum, J. Heterocyclic Chem., 18, 1473-1474 (1981).

 

109)     The Chemistry of Arene Imines. I. Substitution at the Nitrogen Atom of 1a,9b-Dihydro-1H-phenanthro[9,10-b]azirine. M. Weitzberg, Z. Aizenshtat and J. Blum, J. Heterocyclic Chem., 18, 1513-1516 (1981).

 

110)     Substituent Effect of McLafferty Rearrangement of Ionized 2-(Aryl)ethyl Arylacetates. J. Blum, B. Zinger, D. Milstein, O. Buchman and H. Schwarz, Org. Mass. Spectrom. 16, 553-554 (1981).

 

111)     Selective Homogeneous Transfer Hydrogenolysis of Trihalomethyl Compounds by Alcohols and Ruthenium-Phosphine Catalysts. J. Blum, S. Shtelzer, P. Albin and Y. Sasson, J. Mol. Catal., 16, 167-174 (1982).

 

112)     Transfer Hydrogenolysis of Aryl Bromides by Sodium Formate and Palladium-Phosphine Catalyst under Phase Transfer Conditions. R. Bar, Y. Sasson and J. Blum, J. Mol. Catal., 16, 175-180 (1982).

 

113)     Homogeneous Hydrogenation Reactions Catalyzed by RhCl3-Onium Ion Pairs. J. Blum, A. Zoran and Y. Sasson, Proc. 3rd Internat. Symp. Homogeneous Catal., Milano, Aug. 1982, C24 p. 96.

 

114)     Catalytic Hydrogenation and Transfer-Hydrogenation Reactions in Multi-Phase Systems. J. Blum, Proc. 49th Annual Meeting, Isr. Chem. Soc., Oct. 1982, p. 74.

 

115)     Mass Spectrometric Characterization of the Active Sites of Polymer-bound Iridium Complexes in Transfer Hydrogenation Reactions. J. Azran, O. Buchman, G. Hohne, H. Schwarz and J. Blum, J. Mol. Catal., 18, 105-108 (1983).

 

116)     The Chemistry of Polycyclic Arene Imines II. Photochemistry of Phenanthrene 9,10-Imine and Its N-Butyl Derivative. M. Weitzberg, D. Avnir, Z. Aizenshtat and J. Blum, J. Heterocyclic Chem., 20, 1019-1022 (1983).

 

117)     Steroidal cis-Platinum(II) Complexes. New Anticancer Agents with Potential Selectivity. O. Gandolfi, J. Blum and F.M. Shavit, Proc. 4th Internat. Symposium Platinum Coordin. Complexes Cancer Res., Vermont, June 1983, C-4, p. 82.

 

118)     Antileukemic Platinum(II) Catecholamine Complexes. O. Gandolfi and J. Blum, Inorg. Chim. Acta, 80, 103-106 (1983).

 

119)     Catalytic Hydrogenation of Olefins, Acetylenes and Arenes by Rhodium Trichloride and Aliquat-336 under Phase Transfer Conditions. J. Blum, I. Amer, A. Zoran and Y. Sasson, Tetrahedron Lett., 24, 4139-4142  (1983).

 

120)     Transfer Hydrogenolysis of Trichloromethyl Compounds by Alcohols and Polystyrene-Anchored Rh, Ru and Ir Complexes. Y. Migron, J. Blum and Y. Sasson, J. Mol. Catal., 22, 187-194 (1983).

121)     Preparation of Phase Transfer Catalysts by Column Ion Exchange, R. Bar, Y. Sasson and J. Blum, Reactive Polymers, 1, 315-317 (1983).

 

122)     1a,11b-Dihydrobenz[5,6]anthr[1,2-b]azirine. A Non K-Region Polycyclic Arene Imine. J. Blum and S. Ben-Shoshan, J. Heterocyclic Chem., 20, 1461-1464 (1983).

 

123)     Hydrogenation of Aromatic Compounds by a Soluble Rhodium Catalyst under Mild Phase Transfer Conditions. J. Blum, and I.Amer, Proc. Joint Israeli-South African Symp., Surfaces and Catalysis, Jerusalem, Nov. 1983, p. 33.

 

124)     Exceptional Mutagenicity in Bacterial and Mammalian Cells of Aziridines  Derived from Polycyclic Aromatic Hydrocarbons. H. Glatt, I. Yona, S. Ben-Shoshan, P. Jerushalmy, J. Blum and F. Oesch, "Polynuclear Aromatic Hydrocarbons: Eighth International Symposium on Mechanisms, Methods and Metabolism", M.W. Cooke and A.J. Dennis, Eds., Battelle Press, Columbus, Ohio, 1983, pp. 485-496.

 

125)     Quantitative Analysis of Phase-Transfer Catalysts by NMR Spectrometry.  I. Determination of Extraction Constants and Water of Hydration. R. Bar, L. Karpuj-Bar, Y. Sasson and J. Blum, Anal. Chim. Acta, 154,  203-209 (1983).

 

126)     Quantitative Analysis of Phase-Transfer Catalysts by NMR Spectrometry.  II. Formate Selectivity Extraction Constants. R. Bar, L. Karpuj-Bar, Y. Sasson and J. Blum, Anal. Chim. Acta, 154, 313-317 (1983).

 

127)     Antitumor Steroidal-cis-Platinum(II)-o-Catecholato Conjugates:  Preliminary Evaluation on Breast Cancer MCF-7 Cells. O. Gandolfi, J. Blum and F. Mandelbaum-Shavit, Inorg. Chim. Acta, 91, 257-261 (1984).

 

128)     The Chemistry of Arene Imines. III. N-Alkylation of Phenanthrene 9,10-Imine. S. Shtelzer, M. Weitzberg, J. Jeries, T. Sheradsky, Z. Aizenshtat and J. Blum, J. Heterocyclic Chem., 21, 1-3 (1984).

 

129)     Carbonylation and Valence Isomerization of 1,3-Bishomocubane Derivatives by Chlorodicarbonylrhodium Dimer. G. Zlotogorski, J. Blum, E. Osawa, H. Schwarz and G. Hohne, J. Org. Chem., 49, 971-976 (1984).

 

130)     Polymer-Bound Iridium Catalysis. Hydrogen Transfer from Formic Acid to Unsaturated Carbon-Carbon Bonds. J. Azran, O. Buchman, M. Orchin and J. Blum, J. Org. Chem., 49, 1327-1333 (1984).

 

131)     Catalytic Transfer Hydrogenation of Unsaturated Compounds by Solid Sodium Formate in the Presence of Palladium on Carbon. A. Zoran, Y. Sasson and J. Blum, J. Mol. Catal., 26, 321-326 (1984).

 

132)     Transition Metal-Catalyzed Transfer Reduction of Saturated Aldehydes and Ketones under Phase Transfer Conditions. R. Bar, Y. Sasson and J. Blum, J. Mol. Catal., 26, 327-332 (1984).

 

133)     Use of 13C Isotope Shifts for Assignment of Deuterium Labelling Sites in 1,3-Diphenyl-1-propanone. R. Bar, Y. Sasson and J. Blum, Org. Magn. Reson., 22, 565-568 (1984).

 

 

134)     Dichlorobis(triphenylphosphine)palladium(II)-Promoted Hydrogenolysis of Aryl Bromides by Benzyl Alcohol under Phase Transfer Conditions. A.  Zoran, Y. Sasson and J. Blum, J. Mol. Catal., 27, 347-351 (1984).

 

135)     Synthese, Struktur und Katalytische Aktivitat von -Alkylthio- und -Arylthio--chloro-dicarbonyl-bis(tri-tert-butylphosphan)dirhodium-Komplexen. H. Schumann, G. Cielusek, S. Jurgis, E. Hahn, J. Pickardt, J. Blum, Y. Sasson and A. Zoran, Chem. Ber., 117, 2825-2838 (1984).

 

136)     The Chemistry of Arene Imines. IV. An Unusual Silver Promoted Transformation of N-Chlorophenanthrene 9,10-Imine into 9,10-Phenanhrenequinone Dialkyl Acetals. S. Shtelzer, T. Sheradsky, J. Blum and S. Zitrin, J. Heterocyclic Chem., 21, 1593-1595 (1984).

 

137)     The Chemistry of Arene Imines. V. Reactions of Phenanthrene 9,10-Imine with Nucleophiles under Phase Transfer Conditions. M. Weitzberg, Z. Aizenshtat and J. Blum, J. Heterocyclic Chem., 21, 1597-1601 (1984).

 

138)     The Chemistry of Polycyclic Arene Imines. VI. 1-[N,N-Di-(2-propenyl)-9-phenanthrenamine-10-yl]-1a,9b-dihydrophenanthro-[9,10-b]azirine an Unusual Alkylation Product of Phenanthrene 9,10-Imine. M. Weitzberg, Z. Aizenshtat and J. Blum, J. Heterocyclic Chem., 22, 865-868 (1985).

 

139)     Catalytic Activity of Some Homogeneous and Silica-bound Dirhodium Complexes Having One Bridging Sulfur and One Bridging Chloro Ligand. M. Eisen, J. Blum, H. Schumann and S. Jurgis, J. Mol. Catal., 31, 317-326 (1985).

 

140)     Synthese, Struktur und Katalytische Aktivitat von -Alkylthio--chloro-dicarbonylbis(tri-tert-butylarsan)dirhodium-Komplexen. H. Schumann, S. Jurgis, E. Hahn, J. Pickardt, J. Blum and M. Eisen, Chem. Ber., 118, 2738-2745 (1985).

 

141)     Arene Imines. A New Class of Exceptionally Potent Mutagens in Bacterial and Mammalian Cells. H. Glatt, G. Ludewig, K.L. Platt, F. Waechter, I. Yona, S. Ben-Shoshan, P. Jerushalmy, J. Blum and F. Oesch, Cancer Res., 45, 2600-2607 (1985).

 

142)     Phase Transfer Catalyzed Reduction of Aromatic Aldehydes by Aqueous Sodium Formate in the Presence of Dichlorotris(triphenylphosphine)ruthenium(II). A Kinetic Study. R. Bar, L.K. Bar, Y. Sasson and J. Blum, J. Mol. Catal., 33, 161-177 (1985).

 

143)     Hydrogenation of Arenes by the RhCl3-Aliquat 336 Catalyst. 2. Reduction of Naphthalene Derivatives to Tetralins. I. Amer, H. Amer and J. Blum,J. Mol. Catal., 34, 221-228 (1986).

 

144)     Selective Hydrogenation of a,b-Unsaturated Carbonyl Compounds by Rhodium Trichloride and Aliquat-336 in a Two Liquid Phase System. J. Azran, O. Buchman, I. Amer and J. Blum, J. Mol. Catal., 34, 229-234 (1986).

 

145)     Structure-Activity Relationships in the Mutagenicity of N-Substituted Derivatives of Phenanthrene 9,10-Imine. A.A. Stark, E. Zeiger, S. Shtelzler, T. Sheradsky, Y. Lifshitz and J. Blum, Mutagenesis, 1, 35-39 (1986).

 

146)     Palladium-Catalyzed Decomposition of Aqueous Alkali Metal Formate Solutions. H. Wiener, Y. Sasson and J. Blum, J. Mol. Catal., 35, 277-284 (1986).

 

147)     Format Salts as Hydrogen Carriers. H. Wiener, N. Zalmanov, H. Feilchenfeld, Y. Sasson and J. Blum, Proc. lst Internat. Symp. Org Chem. in Technological Perspective, Jerusalem, June, 1986, p. 33.

 

148)     Selective Transfer Hydrogenation of Various Unsaturated Functions by Polymethylhydro-siloxane in the Presence of a Recyclable Rhodium Catalyst. J. Blum, I. Pri-Bar and H. Alper, J. Mol. Catal., 37, 359-369 (1986).

 

149)     Rhodium Trichloride-Aliquat 336 as a Versatile and Recyclable Catalyst. J. Blum, Proc. 52nd Annual Meeting, Isr. Chem. Soc., Ramat-Gan, 1986, p. 66.

 

150)     Oligomerization of Acetylenes by Rh and Ir Catalysts in a Two Liquid Phase System. I. Amer and J. Blum, Proc. 52nd Annual Meeting, Isr. Chem. Soc., Ramat Gan, 1986, p. 69.

 

151)     Nucleophilic Opening of Substituted Phenanthrene K-Region Imines. Theoretical and Experimental Results. S. Shtelzer, A.Y. Meyer, T. Sheradsky and J. Blum, Proc. 52nd Annual Meeting, Isr. Chem. Soc., Ramat-Gan, 1986, p. 94.

 

152)     Mutagenicity of N-Substituted Phenanthrene 9,10-Imines in Salmonella typhimurium and Chinese Hamster V79 Cells. H. Glatt, S. Shtelzer, T. Sheradsky, J. Blum and F. Oesch, Environ. Mutagenesis, 8, 829-837 (1986).

 

153)     Aminomalonato(1,2-diaminocyclohexane)platinum(II): A Competitive Antitumor Compound Within a New Class of Neutral, Chemically Stable, Water Soluble, Functionalized Platinum Complexes. O. Gandolfi, H.C. Apfelbaum and J. Blum, Inorg. Chim. Acta, 135, 27-31 (1987).

 

154)     Hydrogenation of Arenes by the RhCl3-Aliquat 336 Catalyst. Part 3.  Selective Reduction of Polycyclic Compounds. I. Amer, H. Amer, R. Ascher, J. Blum, Y. Sasson and K.P.C. Vollhardt, J. Mol. Catal., 39, 185-194 (1987).

 

155)     Syntheses and Chemistry of Some Dibenz[c,e]azepines. M. Weitzberg, E. Abu-Shakra, A. Azeb, Z. Aizenshtat and J. Blum, J. Org. Chem., 52, 529-536 (1987).

 

156)     A Facile Synthesis of a,a,w,w-Tetrahalo-a,w-dicarboxylic Esters. Y. Migron, J. Blum and J. Bar-Tana, Tetrahedron, 43, 361-364 (1987).

 

157)     Selective C-C Bond Hydrogenation in Unsaturated Nitro Compounds in the Presence of the RhCl3-Aliquat 336 Catalyst System. I. Amer, T. Bravdo, J. Blum and K.P.C. Vollhardt, Tetrahedron Lett., 28, 1321-1322 (1987).

 

158)     Hydrogenation of Arenes by the RhCl3-Aliquat 336 Catalyst, Part 4. Hydrogen-Deuterium Exchange and Other Mechanistic Features. J. Blum, I. Amer, K.P.C. Vollhardt, H. Schwarz and G. Hohne, J. Org. Chem., 52, 2804-2813 (1987).

 

159)     The Remarkable Catalytic Properties of the RhCl3-Aliquat 336 Ion Pair. J. Blum, Proc. 3rd Internat. Conference on the Chemistry of the Platinum Group Metals. Sheffield, July 1987, O-18.

 

160)     The Steric Course of Aziridine Ring Opening in Substituted Phenanthrene Oxides and Imines. A Probe for the Reaction of Arene Imines with Cellular Nucleophiles. J. Blum, S. Shtelzer, A.Y. Meyer and T. Sheradsky, Proc. 11th Internat. Congress on Heterocyclic Chem., Heidelberg, Aug. 1987, p. 330.

 

161)     Catalytic Activity of Some Immobilized Dirhodium Complexes with One Bridging Thiolato and One Bridging Chloro Ligand. M. Eisen, T. Bernstein, J. Blum and H. Schumann, J. Mol. Catal., 43, 199-212 (1987).

 

162)     The Chemistry of Polycyclic Arene Imines. VII. Reactions of Phenanthrene 9,10-Imine with Aromatic Carboxaldehydes, Carboxylic Acids and Acetylenic Esters. S. Shtelzer, T. Sheradsky and J. Blum, J. Heterocyclic Chem., 24, 1581-1585 (1987).

 

163)     Regioselectivity of Nucleophilic Ring Opening in Substituted Phenanthrene 9,10-Imine and 9,10-Oxide. Molecular Orbital Theoretical Predictions and Experimental Results. S. Shtelzer, A.Y. Meyer, T. Sheradsky and J. Blum, J. Org. Chem., 53, 161-166 (1988).

 

164)     Polycyclic Arene Imines and Chemical Mutagenesis. J. Blum, Proc. 53rd Annual Meeting, Isr. Chem. Soc., Beer-Sheva, Feb. 1988, p. 86.

 

165)     Metallocene Conjugates of cis-Platinum-Catecholato Complexes with Target Specificity. H.C. Apfelbaum, M. Wenzel and J. Blum, Proc. 53rd Annual Meeting, Isr. Chem. Soc., Beer-Sheva, Feb. 1988, p. 163.

 

166)     Preparation and Catalytic Activity of Supported Dirhodium Complexes with One -Cl and One -SR Ligands. M. Eisen, T. Bernstein, J. Blum and H. Schumann, Proc. 53rd Annual Meeting, Isr. Chem. Soc., Beer-Sheva, Feb. 1988, p. 164.

 

167)     Disproportionation and Dehydrogenation of 1,3-Cyclohexadienes in the Presence of Recyclable RhCl3-Quaternary Ammonium Salt Catalysts. I. Amer, V. Orshav and J. Blum, J. Mol. Catal., 45, 207-214 (1988).

 

168)     The Heterogeneous Catalytic Hydrogenation of Bicarbonate to Formate in Aqueous Solutions. H. Wiener, J. Blum, H. Feilchenfeld, Y. Sasson and N. Zalmanov, J. Catal., 110, 184-190 (1988).

 

169)     cis-Platinum-o-Catecholato Conjugate Labelled with 130[Ru]-Ruthenocene Residue. H.C. Apfelbaum, J. Blum and M. Wenzel, J. Labelled Compd. Radiopharm., 27, 75-83 (1989).

 

170)     K-Imine Derivatives of Chrysene, Benzo[c]phenanthrene and 7,12-Dimethylbenz[a]-anthracene. E. Abu-Shqara and J. Blum, Proc. 54th Anual Meeting, Isr. Chem. Soc., Rehovot, Feb. 1989, p. 39.

 

171)     Formation, Structure Determination and Theoretical Studies of Two Unusual Sulfur and Carbonyl Bridged Dirhodium Complexes. H. Schumann, S. Jurgis, M. Eisen and J. Blum, Proc. 54th Annual Meeting, Isr. Chem. Soc., Rehovot, Feb. 1989, p. 42.

 

172)     Asymmetric Hydrogenation Catalyzed by Homogeneous and Immobilized Cl- and SR-Bridged Dirhodium Complexes. M. Eisen, J. Blum and H. Schumann, Proc. 54th Annual Meeting, Isr. Chem. Soc., Rehovot, Feb. 1989, p. 43.

 

173)     The Synthesis of 4b,5a-Dihydro-5H-benzo[3,4]phenanthro[1,2-b]azirine and 1a,11b-Dihydro-6,11-dimethyl-1H-benz[3,4]anthra[1,2-b]azirine. E. Abu-Shqara and J. Blum, J. Heterocyclic Chem., 26, 377-379 (1989).

 

174)     Synthesis of cis-Dichlorodiammineplatinum Analogs Having Steroidal Hormones Bound to the Metal Atom via Malonato Bridges. O. Gandolfi, H.C. Apfelbaum, Y. Migron and J. Blum, Inorg. Chim. Acta, 161, 113-123 (1989).

 

175)     Evidence for Exchange Processes Associated with the Hydrogenation of Z-Methyl a-Acetamidocinnamate by a Silica-Bound Chiral Dirhodium Catalyst. M. Eisen, J. Blum, G. Hohne, H. Schumann and H. Schwarz, Chem. Ber. 122, 1599-1601 (1989).

 

176)     K-Region Imines of Benzo[h]quinoline, Benzo[f]quinoline and 1,10-Phenanthroline, E. Abu-Shqara and J. Blum, Proc. 12th Internat. Congress on Heterocyclic Chem., Jerusalem, Aug. 1989, p. A3.

 

177)     Synthesis, Hypolipidemic and Antidiabetogenic Activities of b,b'-Tetra-substituted, Long-chain Dioic Acids. J. Bar-Tana, S. Ben-Shoshan, J. Blum, Y. Migron, R. Hertz, J. Phill, G. Rose-Kahn and E.-C. Witte, J. Med. Chem., 32, 2072-2084 (1989).

 

178)     Catalytic Asymmetric Hydrogenation by Some Homogeneous and Silica-Bound -Thiolato--chlorodicarbonylbis(neomenthyldiphenylphosphine)dirhodium Complexes. M. Eisen, J. Blum, H. Schumann and B. Gorella, J. Mol. Catal., 56, 329-337 (1989).

 

179)     Structure-Activity Relationships in Mutagenicity and in Nucleophilic Ring Opening of N-(Arylmethyl)phenanthrene 9,10-Imines. M. Roll, S. Shtelzer, A.-A. Stark and J. Blum, Mutagenesis, 5, 25-30 (1990).

 

180)     Synthesis and Catalytic Activity of Some Homogeneous and Immobilized Chiral Dirhodium Complexes. M. Eisen, P. Weitz, S. Shtelzer, B. Gorella, H. Schumann and J. Blum, Proc. 55th Annual Meeting, Isr. Chem. Soc. Tel-Aviv Feb. 1990, p. 13.

 

181)     Catalytic Rearrangement and Cyclooligomerization of Phenylated Diynes by Water Soluble Rh and Pt Compounds Under Phase Transfer Conditions. Y. Badrieh, I. Amer and J. Blum, Proc. 55th Annual Meeting, Isr. Chem. Soc., Tel Aviv, Feb. 1990, p. 65.

 

182)     Multinuclear (195Pt, 15N, 13C) NMR Studies of the Reaction between cis-Diaminediaquaplatinum(II) and Aminomalonate. D. Gibson, A. Rosenfeld, H.C. Apfelbaum and J. Blum, Proc. 55th Annual Meeting, Isr. Chem. Soc., Tel Aviv Feb. 1990, p. 81.

 

183)     Synthesis and Structure Determination of Two Unusual Dirhodium Complexes Having Thiolato and Carbonyl Bridging Ligands. H. Schumann, S. Jurgis, M. Eisen and J. Blum, Inorg. Chim. Acta, 172, 191-201 (1990).

 

184)     Oligomerization of Alkynes by the RhCl3-Aliquat 336 Catalyst System. Part 1. Formation of Benzene Derivatives. I. Amer. T. Bernstein, M. Eisen, J. Blum and K.P.C. Vollhardt, J. Mol. Catal., 60, 313-321 (1990).

 

185)     Oligomerization of Alkynes by the RhCl3-Aliquat 336 Catalyst System. Part 2. Formation of 2,3-Disubstituted 1-Phenylnaphthalenes by Cyclodimerization of Phenylalkynes, I. Amer, J. Blum and K.P.C.  Vollhardt, J. Mol. Catal., 60, 323-330 (1990).

 

186)     Transition Metal Catalyzed Synthesis of Polycyclic Arenes from Phenylalkynes under Phase Transfer Conditions, Y. Badrieh, I. Amer and J. Blum, "Frontiers in Chemistry", (TUB-Dokumentation, Kongresse und Tagungen), 50, 89-91 (1990).

 

187)     Arene Imine Derivatives of Nitrogen Heterocycles; 1a,9b-Dihydrobenz[h]azirino[f]-quinoline, 1a,9b-Dihydrobenz[f]azirino[h]quinoline and 1a,9b-Dihydroazirino[f][1,10]-phenanthroline, E. Abu-Shqara and J. Blum, J. Heterocyclic Chem., 27, 1197-1200 (1990).

 

188)     Disproportionation of 1,3-Cyclohexadiene and 1,2-Dihydronaphthalene Derivatives by a Silica-Bound Dirhodium Catalyst, M. Eisen, T. Korpal, J. Blum and H. Schumann, J. Mol. Catal., 61, 19-25 (1990).

 

189)     On the Chemistry and Antitumor Activity of Plaltinumdiamine Complexes of Dicarboxylates. D. Gibson, A. Rosenfeld, H.C. Apfelbaum and J. Blum, Proc. 9th Internat. Symposium on Medicinal Chemistry, Jerusalem, Sept. 1990, p. 52.

 

190)     Catalytic Transformation of Phenylalkynes to Mono- and Polycyclic Arenes by Water Soluble Rhodium and Platinum Compounds under Phase Transfer Conditions, J. Blum, Y. Badrieh, I. Amer and K.P.C. Vollhardt, Proc. 7th Internat. Symposium on Homogeneous Catalysis, Lyon, Sept. 1990. pp. 211-212.

 

191)     Multinuclear (195Pt, 15N, 13C) NMR Studies of the Reaction between cis-Diaminediaquaplatinum(II) and Aminomalonate, D. Gibson, A. Rosenfeld, H.C. Apfelbaum and J. Blum, Inorg. Chem., 29, 5125-5129 (1990).

 

192)     Arene Imine Derivatives of Chrysene and Benzo[g]chrysene: 1a,11c-Dihydrochryseno[5,6-b]azirine and 1a,13c-Dihydrobenzo[11,12]chryseno[5,6-b]azirine, E. Abu-Shqara, S. Elg'amal and J. Blum, J. Heterocyclic Chem., 27, 1681-1684 (1990).

 

193)     Some Unusual Transformations of 1,2-Bis(phenylethynyl)benzene to Polycyclic Compounds. Y. Badrieh, A. Greenwald, J. Blum and H. Schumann. Proc. 56th Annual Meeting, Isr. Chem. Soc., Jerusalem, Feb. 1991, p. 75.

 

194)     Platinum(IV) Chloride-Catalyzed Rearrangement of Conjugated Alkynones. Y. Badrieh, A. Kayyal and J. Blum, Proc. 56th Annual Meeting, Isr. Chem. Soc., Jerusalem, Feb. 1991, p. 76.

 

195)     The Selective Aerobic Oxidative Dehydrogenation of Alcohols and Amines Catalyzed by Heteropoly Molybdates, PMo10V2O405- and CeMo12O428-. R. Neumann, M. Levin and J. Blum, Proc. 56th Annual Meeting, Isr. Chem. Soc., Jerusalem, Feb. 1991, p. 114.

 

196)     The Syntheses of 4b,5a-Dihydrodibenz[3,4:5,6]anthra[1,2-b]oxirene and 4b,5a-Dihydro-5H-dibenz[3,4:5,6]anthra[1,2-b]azirine, E. Abu-Shqara and J. Blum, J. Heterocyclic Chem., 28, 473-475 (1991).

 

197)     Cyclooligomerization and Rearangement of Some Phenylated Diynes by the RhCl3-Aliquat 336 and by the H2PtCl6-Aliquat 336 Catalysts under Phase Transfer Conditions, Y. Badrieh, J. Blum, I. Amer and K.P.C. Vollhardt, J. Mol. Catal., 66, 295-312 (1991).

 

198)     Transfer Hydrogenation of Diaryl-Acetylenes by Polymethylhydrosiloxane in the Presence of the RhCl3-Aliquat 336 Catalyst. J. Blum, G. Bitan, S. Marx and K.P.C. Vollhardt, J. Mol. Catal., 66, 313-319 (1991).

 

199)     Studies on the Mechanism of Transfer Hydrogenation of Nitroarenes by Format Salts Catalyzed by Pd/C, H. Wiener, J. Blum and Y. Sasson, J. Org. Chem., 56, 4481-4486 (1991).

 

200)     Synthesis, Structure Determination and Catalytic Acitivity of (+)-cis-[Dicarbonyl--chloro--[5b-methyl-2a-(1-methylethyl)cyclo-hexanethio]]bis[tris(1,1-dimethylethyl]arsine]-dirhodium, H. Schumann,  B. Gorella, M. Eisen and J. Blum, J. Organomet. Chem., 412, 251-258 (1991).

 

201)     Preparation and Anticancer Activity of Two Tryptamine Derived Platinum Complexes, H. Apfelbaum, J. Blum and F. Mandelbaum-Shavit, Inorg. Chim. Acta, 186, 243-246 (1991).

 

202)     Synthesis, Structure Determination and Immobilization of Some Dirhodium Complexes with  Chiral Bridging Thiolate Ligands. Investigation of their Catalytic Activity for Enantioselective Hydrogenation, M. Eisen, P. Weitz, S. Shtelzer, J. Blum, H. Schumann, B. Gorella and F.H.  Gorlitz, Inorg. Chim. Acta, 188, 167-176 (1991).

 

203)     Transfer Hydrogenolysis of Aryl Halides and Other Hydrogen Acceptors by Formate Salts in the Presence of Pd/C Catalyst, H. Wiener, J. Blum and Y. Sasson, J. Org. Chem., 56, 6145-6148 (1991).

 

204)     Strong Influence of the Exposure Medium on the Mutagenicity in the Ames Test: 7-Methylbenz[a]anthracene 5,6-Oxide, H. Glatt, U. Martine, W. Baidossi and J. Blum, Mutagenesis, 6, 537-540 (1991).

 

205)     Some Unusual Reactions of 1,2-Bis(phenylethynyl)benzene with Sulfur, Carbon Monoxide and Acetylene-dicarboxylic Esters, Y. Badrieh, A. Greenwald, H. Schumann and J. Blum, Chem. Ber., 125, 667-674 (1992).

 

206)     Selective Catalytic Transformation of Phenylacetylene by Some Water Soluble Rhodium Catalysts, W. Baidossi, H. Hemling, T. Achituv, H. Schumann and J. Blum, Proc. 57th Annual Meeting, Isr. Chem. Soc., Haifa, Feb. 1992, p. L-11.

 

207)     Hydration of Alkynes by RhCl3 and Quaternary Ammonium Salts and by Related Transition Metal Compounds, H. Huminer, M. Hodzaev, H. Alper and J. Blum, Proc. 57th Annual Meeting, Isr. Chem. Soc., Haifa, Feb. 1992, p. P-8.

 

208)     Antileukemic Ferrocene-bound Malonato-platinum(II) Complexes, A. Rosenfeld, D. Gibson, A. Ramu and J. Blum, Proc. 57th Annual Meeting, Isr. Chem. Soc., Haifa, Feb. 1992, p. P-58.

 

209)     Reductive Alkylation of Polycyclic Hydrocarbons, Deoxygenation of Arene Oxides and Deamination of Arene Imines via Aromatic Dianions, O. Elmalak, J. Blum and M. Rabinovitz, Proc. 57th Annual Meeting, Isr. Chem. Soc., Haifa, Feb. 1992, p. P-59.

 

210)     A New Synthesis of Hydrophilic Carboxylated Arylphosphines, V. Ravindar, H. Hemling, H. Schumann and J. Blum, Synth. Commun., 22,  841-851 (1992).

 

211)     Alkyne Hydration Promoted by RhCl3 and Quaternary Ammonium Salts. J. Blum, H. Huminer and H. Alper, J. Mol. Catal., 75, 153-160 (1992).

 

212)     (a) Rearrangement, Hydrochlorination and Hydration of Conjugated Alkynones by Platinum(IV) Compounds under Homogeneous and under Biphasic Conditions, Y. Badrieh, A. Kayyal and J. Blum, Proc. 7th Internat. Symp. on Relations between Homogeneous and Heterogeneous Catalysis, Tokyo, May 1992, pp. 282-283; (b) J. Mol. Catal., 75, 161-167 (1992).

 

213)     A Novel Convenient Synthesis of Aryl Phosphines Containing Reactive Functional groups, V. Ravindar, H. Hemling, H. Schumann and J. Blum, Synth. Commun., 22, 1453-1459 (1992).

 

214)     Rh and Pt-Catalyzed Addition of CO, S and Active Acetylenes to 1,2-Bis(phenylethynyl)-benzene, Y. Badrieh, A. Greenwald, H. Schumann and J. Blum, Proc. 8th International Symposium on Homogeneous Catalysis, Amsterdam, Aug 1992, P-26.

 

215)     Catalytic Activity of cis-[-[Bis(1,1-dimethylethyl)phosphino]]dicarbonyl--chlorobis[tris(-1,1-dimethylethyl)phosphine]dirhodium and of its chiral analog (+)-cis[-[Bis(1,1-dimethylethyl)phosphino]]dicarbonyl--chloro-bis[[5b-methyl-2a-(1a-methylethyl)cyclohexyl]-diphenylphosphine]dirhodium, E. Berkovich, A. Jacobson, J. Blum, H. Schumann, M. Schafers and H. Hemling, J. Organomet. Chem., 436, 95-100 (1992).

 

216)     Preparation, Characterization and Antileukemic Properties of Diamine-malonatoplatinum(II) Complexes Tethered to Ferrocene, A. Rosenfeld, D. Gibson, A. Ramu and J. Blum, Inorg. Chem. Acta, 201, 219-222 (1992).

 

217)     Alkali Metal Mediated Conversion of Arene Oxides and Arene Imines into Aromatic Hydrocarbons, O. Elmalak, M. Rabinovitz and J. Blum, J. Heterocyclic Chem., 30, 291-292 (1993).

 

218)     Sol-Gel Encapsulated Transition Metal Quaternary Ammonium Ion Pairs as Highly Efficient Recyclable Catalysts, A. Rosenfeld, D. Avnir and J. Blum, J. Chem. Soc., Chem. Commun., 583-584 (1993).

 

219)     Arene Oxide and Arene Imine Derivatives of Carcinogenic Sulfur Heterocycles, Y. Shalom and J. Blum, Proc. 58th Annual Meeting Isr. Chem. Soc., Ramat Gan, Feb. 1993, P-6.

   

220)     RhCl3- and PtCl4-Catalyzed Reactions of 1,8-Bis(ethynyl)naphthalenes with CO, Y. Badrieh, K. Totland and J. Blum, Proc. 58th Annual Meeting Isr. Chem. Soc., Ramat Gan, Feb. 1993, P-34.

 

221)     A New PtCl4-Catalyzed Transformation of Enynes into Bicycloheptenes, H. Beer, Y. Badrieh and J. Blum, Proc. 58th Annual Meeting Isr. Chem. Soc., Ramat Gan, Feb. 1993, P-35.

 

222)     Trapping of Organic Molecules in Ceramic Matrices - Environmental, Biochemical and Catalytic Applications, D. Avnir, J. Blum, S. Braun, O. Lev and M. Ottolenghi, Proc. 58th Annual Meeting Isr. Chem. Soc., Ramat Gan, Feb. 1993, IN-3.

 

223)     On the Various Modes of Interaction of Sulfur with Polyphenylated Diynes, J. Blum, Y. Badrieh, O. Shaaya, L. Meltser and H. Schumann, Phosphorus, Sulfur, Silicon, 79, 87-96 (1993).

 

224)     Lithium Diphenylphosphide Mediated Sulfur Bridge Exchange by Phosphorus in [Rh(CO)PR3]2(-Cl)(-SR), E. Berkovich, H. Schumann and J. Blum, Proc. 5th Internat. Conference on the Chemistry of the Platinum Group Metals, St. Andrews, July 1993, p. C. 174.

 

225)     Sol-Gel Entrapped Ion Pairs of Group VIII Elements and Quaternary Ammonium Salts as Recyclable Hydrogen Transfer Catalysts, J. Blum, A. Rosenfeld and D. Avnir, Proc. 1st Europ. Congress Catal., Montpellier, Sept. 1993, p. 327.

 

226)     A New PtCl4-Catalyzed Cyclorearrangement of Enynes. J. Blum, H. Beer and Y. Badrieh, Proc. 1st Europ. Congress Catal., Montpellier, Sept. 1993, p. 332.

 

227)     Homogeneous and Biphasic Oligomerization of Terminal Alkynes by Some Water Soluble Rhodium Catalysts, W. Baidossi, N. Goren, J. Blum, H. Schumann and H. Hemling, J. Mol. Catal., 85, 153-162 (1993).

 

228)     A Convenient Route to 1,3,5-Trisubstituted Benzenes via Rhodium Catalyzed Polymerization of Acetylenes, I. Amer, H. Schumann, V. Ravindar, W. Baidossi, N. Goren and J. Blum, J. Mol. Catal., 85, 163-171 (1993).

 

229)     K-Region Oxides and Imines of Benzo[b]phenanthro[2,3-d]thiophene and Benzo[b]-phenanthro[3,2-d]thiophene, J. Blum, Y. Shalom and R.G. Harvey, J. Heterocyclic Chem., 30, 1521-1523 (1993).

 

230)     The Versatility of Metal Halide-Quaternary Ammonium Salt Catalysts for Organic Processes.  From Homogeneous to Glass-Encapsulated Ion Pairs. J. Blum, Russ. Chem. Bull., 42, 1619-1627 (1993). 

 

231)     Tellurium-Mediated Halogen Transfer from Haloalkanes to a Diyne, Y. Badrieh, F. Malem and J. Blum,  Proc. 59th Annual Meeting, Isr. Chem. Soc., Beer-Sheva, Jan. 1994, p. 100.

 

232)     Arene Imine Derivatives of Benz[c]- Dibenz[a,h]- and Dibenz[c,h]acridine, N. Bazanov and J. Blum,  Proc. 59th Annual Meeting, Isr. Chem. Soc., Beer-Sheva, Jan. 1994, p. 101. 

 

233)     Catalytic Transformation of Phenylated Diynes to New Polycyclic Systems by RhCl3 and PtCl4-Aliquat 336 Ion Pairs, W. Baidossi and J. Blum, Proc. 59th Annual Meeting, Isr. Chem. Soc., Beer-Sheva, Jan. 1994, p. 102.

 

234)     Polymer-Supported Ion Pairs of Transition Metal Salts and Dowex 1.  A New Class of Recyclable Catalysts, M. Setty-Fichman, K. Kupferman, J. Blum and Y. Sasson, Proc. 59th Annual Meeting, Isr. Chem. Soc., Beer-Sheva, Jan. 1994, p. 164.

 

235)     Polystyrene-Supported RhCl3-Quaternary Ammonium Ion Pair as a Long-Lived Efficient and Recyclable Catalyst, M. Setty-Fichman, J. Blum, Y. Sasson and M. Eisen, Tetrahedron Lett., 35, 781-784 (1994).

 

236)     Interconversion of syn-{[(Me3C)3PRh(CO)]2(-Cl)(-SR)} and syn-{[Me3C))3-PRh(CO)]2(-Cl)(-PR2)} through Exchange of Bridging Ligands. A Case of Sterically Inactivated Chloro Bridges in Dirhodium Complexes, E. Berkovich, J. Blum and H. Schumann, J. Organomet. Chem., 469, 111-113 (1994).

 

237)     Effects of Changes in the Ligands on the Skeleton and the Catalytic Activity of Some New Rhodium Complexes with Pyrazolato Moieties, H. Schumann, H. Hemling, V. Ravindar, Y. Badrieh and J. Blum, J. Organomet. Chem., 469, 213-219 (1994).

238)     Mutagenicity of K-Region Oxides and Imines of Chrysene, Benzo[c]phenanthrene and Benzo[g]chrysene in Salmonella typhimurium, H. Glatt, E. Abu-Shqara, R.G. Harvey and J. Blum, Mutat. Res., 308, 135-141 (1994).

 

239)     K-Region Oxides and Imines Derived from Alkylated Benz[a]anthracene Congeners: Synthesis, Stability in Aqueous Media, and Mutagenicity, H.R. Glatt, E. Abu-Shqara, U. Martine, W. Baidossi, R.G. Harvey and J. Blum, Mutagenesis, 9, 83-92 (1994).

 

240)     Further Observation on RhCl3-Aliquat 336 Catalyzed Carbonylation of Aromatic Diynes under Phase Transfer Conditions, Y. Badrieh, J. Blum and H. Schumann, J. Mol. Catal., 90, 231-244 (1994).

 

241)     The Presence of KCl in the Exposure Medium Strongly Influences the Mutagenicity of Metabolites of Polycyclic Aromatic Hydrocarbons in Escherichia coli, H. Glatt, A. Staffa-Piee, N. Enders, W. Baidossi and J. Blum,  Mutat. Res., 324, 111-114 (1994).  

 

242)     On the Regioselectivity in Transformation of Benzo[a]pyrene 4,5-Oxide  and 3-Methylchol-anthrene 11,12-Oxide to the Corresponding b-Amino-Alcohol Derivatives.  J. Blum, M. Setty-Fichman, L. Efron, S. Shaik and R.G. Harvey, Tetrahedron,  50, 8505-8514 (1994).

 

243)     RhCl3- and PtCl4-Catalyzed Transformations of Phenylated Diynes to New Condensed Polycyclic Compounds.  W. Baidossi, H. Schumann and J. Blum, Proc. 9th Internat. Symp. Homogeneous Catal., Jerusalem, Aug. 1994, pp. 130-131.       

 

244)     Sol-Gel Entrapment of Homogeneous Organometallic Catalysts. D. Avnir, J. Blum, A. Rosenfeld, H. Schumann, H. Sertchook and S. Wernik. Proc.  9th Internat. Symp. Homogeneous Catal., Jerusalem, Aug. 1994, pp. 144-145.

 

245)     Mono-, and Dibenzacridine Imines.  Synthesis of 1a,11b-Dihydrobenz[c]azirino[a]acridine, 4b,5a-Dihydrodibenz[c,h]azirino[a]acridine and 1a,13b-Dihydrobenz[c,j]azirino[a]acridine,  N. Bazanov, Y. Dayan, J. Blum and R.G. Harvey,  J. Heterocyclic Chem., 31, 837-839 (1994). 

 

246)     Dicarbonylbis[2-(diphenylphosphino)-N,N-dimethylethanamine)]bis[-(2-methyl-2-propanethiolato)dirhodium and [Dicarbonylbis[2-(diphenylphosphino)-N,N,N-trimethyl-ethanaminium]bis[-(2-methyl-2-propanethiolato)]dirhodium Tetraphenylborate. Their Syntheses, Characterization, and Application as Hydrogenation Catalysts.  H Schumann, H. Hemling, N. Goren and J. Blum, J. Organomet. Chem., 485, 209-213 (1995).

 

247)     Organic Synthesis by Homogeneous and Heterogenized Transition Metal-Ammonium Ion Pair Catalysts.  J. Blum, Proc. 60th Annual Meeting, Isr. Chem. Soc., Rehovot, Feb. 1995, p. 57.

 

248)     Tellurium-Mediated Halogen Transfer from Polyhaloalkanes to Diyne Acceptors.  J. Blum, W. Baidossi, Y. Badrieh, R.E. Hoffman and H. Schumann, J. Org. Chem., 60, 4738-4742 (1995).

 

249)     Stabilized Dialkylaluminium Complexes as Alkylating Agents.  J. Blum, W. Baidossi, A. Rosenfeld, M. Frick, B. Heymer, S. Schutte and H. Schumann, Proc. 8th IUPAC Symposium, Santa Barbara, Aug. 1995, p. 161.

 

 

250)     A Novel PtCl4-Catalyzed Cyclorearrangement of Allyl Propynyl Ethers to 3-Oxabicyclo-[4.1.0]heptenes.  J. Blum, H. Beer-Kraft and Y. Badrieh, J. Org. Chem., 60,  5567-5569 (1995).

 

251)     Sol-Gel Entrapped RhCl3-Quaternary Ammonium Ion-Pair Catalyzed Hydrogenation, Hydroformylation and Disproportionation Processes.  A. Rosenfeld, D. Avnir and J. Blum.  Proc. 2nd Europ. Congress Catal., Masstrich, Sept. 1995, p. 751.

 

252)     Synthesis and Structure Determination of Some Platinum(II) Complexes with Hydrophilic Carboxylated Tertiary Phosphine Ligands.  V. Ravindar, H. Schumann, H. Hemling and J. Blum., Inorg. Chim. Acta, 240, 145-152 (1995).

 

253)     Comparison between Homogeneous and Sol-Gel-Encapsulated Rhodium-Quaternary Ammonium Ion Pair Catalysts.  J. Blum, R. Rosenfeld, N. Polak, O. Israelson, H. Schumann and D. Avnir. (a) J. Mol. Catal. A., 107, 217-223 (1996); (b) Proc. 8th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis, Balatonfured, Hungary, Sept. 1995, p. O-13.

 

254)     Adducts of a Polycyclic Arene Imine to Some Purines and Pyrimidines.  Y. Shalom, R.G. Harvey and J. Blum Proc. 15th Internat. Symposium on Polycyclic Aromatic Compounds, Belgirate, Italy, Sept. 1995, p. 53.

 

255)     Polycyclic Arene Sulfides.  Prepraration of 1a,2,3,11b-Tetrahydrobenz[5,6]anthra[1,2-b]-thiirene, 6b,7a,8,9-Tetrahydrobenzo[10,11]chryseno[1,2-b]thiirene, and 7,8,8a,9a-Tetra- hydrobenzo[10,11]chryseno[3,4-b]thiirene.  Y. Shalom, V. Kogan, Y. Badrieh, R.G. Harvey and J. Blum, J. Heterocyclic Chem., 33, 53-55 (1996).

 

256)     Sol-Gel Entrapped Lipophlic and Hydrophilic Ruthenium-, Rhodium- and Iridium-Phosphine Complexes as Recyclable Isomerization Catalysts.  H. Sertchook, D. Avnir, J. Blum, F. Jo, A. Ktho, H. Schumann, R. Weimann and S. Wernik, J. Mol. Catal. A., 108, 153-160 (1996).

 

257)     PtCl4/CO-Catalyzed Hydration of Alkynes.  W. Baidossi, M. Lahav and J. Blum.  Proc. 61st Annual Meeting, Isr. Chem. Soc., Jerusalem, Feb. 1996, p. 47.

 

258)     Some Applications of Stabilized Dimethylaluminum Complexes in Organic Synthesis.  W. Baidossi, A. Rosenfeld, M. Eshel, H. Schumann and J. Blum. Proc. 61st Annual Meeting, Isr. Chem. Soc., Jerusalem, Feb. 1996, p. 62.

 

259)     Resolution of Carcinogenic Polycyclic Arene Imines.  Y. Cohen, S. Levin and J. Blum. Proc. 61st Annual Meeting, Isr. Chem. Soc., Jerusalem, Feb. 1996, p. 69.

 

260)     Hydrogenation, Hydroformylation and Disproportionation Processes Catalyzed by Some Sol-Gel Entrapped RhCl3-Quaternary Ammonium Ion-Pairs.  A. Rosenfeld, J. Blum and D. Avnir. Proc. 61st Annual Meeting, Isr. Chem. Soc., Jerusalem, Feb. 1996, p. 104.

 

261)     Adducts of a Phenanthrene 9,10-Imine Derivative to Some Ribonucleosides.  Y. Shalom, R.G. Harvey and J. Blum.  Proc. 61st Annual Meeting, Isr. Chem. Soc., Jerusalem, Feb. 1996, p. 111.

 

262)     [(3-Dimethylamino)propyl]dimethylaluminum.  A Convenient Reagent for Methylation and Ethynylation of Carbonyl Compounds.  W. Baidossi, A. Rosenfeld, B.C. Wassermann, S. Schutte, H. Schumann and J. Blum.  Synthesis, 1127-1130 (1996).

 

263)     Selective Transformations of Phenylated Diynes to Polycyclic Compounds by the RhCl3- and PtCl4-Aliquat 336 Ion Pair Catalysts.  W. Baidossi, H. Schumann and J. Blum.  Tetrahedron, 52, 8349-8364 (1996).

 

264)     Adducts of Phenanthrene 9,10-Imine and Benz[a]anthracene 5,6-Imine to Some Nitrogen Heterocycles.  Y. Shalom, R.G. Harvey and J. Blum.  J. Heterocyclic Chem., 33, 681-686 (1996).

 

265)     Palladium-Catalyzed Alkylation of Aryl and Vinyl Halides by Stabilized Organoaluminum and Organogallium Complexes.  J. Blum, W. Baidossi, E. Shakh, M. Frick, B. Heymer, S. Schutte and H. Schumann.  Proc. 10th International Symp. on Homogeneous Catal., Princeton, NJ, August, 1996, A-16.

 

266)     Organoaluminum and Organogallium Complexes as Efficient and Selective Alkylating Agents.  W. Baidossi, J. Blum, M. Frick, D. Gelman, B. Heymer, H. Schumann, S. Schutte and E. Shakh. Proc. 5th Symposium on Organic Synthesis via Organometallics (OSM5) Heidelberg, Sept. 1996, L3.

 

267)     Sol-Gel Encapsulated Transition Metal Compounds as Highly Stable, Effective and Recyclable Catalysts.  D. Avnir, J. Blum, A. Rosenfeld, H. Schumann, H. Sertchook, R. Weimann and S. Wernik, Proc. 5th Symposium on Organic Synthesis via Organometallics (OSM5) Heidelberg, Sept. 1996, P1.

 

268)     Disproportionation of Dihydroarenes by Sol-Gel Entrapped RhCl3-Quaternary Ammonium Ion Pair Catalysts.  A. Rosenfeld, J. Blum and D. Avnir, J. Catalysis, 164, 363-368 (1996).

 

269)     Adducts of Polycyclic Arene Imines to Some Purines and Pyrimidines.  Y. Shalom, R.G. Harvey and J. Blum, Polycyclic Aromatic Compounds, 10, 179-185 (1996).

 

270)     Further Studies on Heterocyclic Arene Imines.  Preparation of 1a,9b-Dihydroazirino[f][1,7]phenanthroline, 3b,4a-Dihydroazirino[2,3]phenaleno[1,9-g,h]-quinoline and 1a,13b-Dihydrobenzo[1,2:6,7]phenazino[1,2-b]azirine.  N. Bazanov-Katz, R. Zangi and J. Blum.  J. Heterocyclic Chem., 33, 1703-1705 (1996).

 

271)     Hydration of Alkynes by a PtCl4-CO Catalyst.  W. Baidossi, M. Lahav, and J. Blum, J. Org. Chem., 66, 669-672 (1997).

 

272)     Effect of the CO2H Groups of Carboxylated Triarylphosphines on (COD)RhCl(PAr3)-Catalyzed Isomerization of 1-Octen-3-ol under Phase Transfer Conditions, H. Schumann, V. Ravindar, L. Meltser, W. Baidossi, Y. Sasson and J. Blum, J. Mol. Catal. A: Chem.,  118, 55-61 (1997).

 

273)     Epoxidation of Polyaromatics Using HOF.CH3CN. S. Rozen, Y. Bareket and J. Blum, Tetrahedron Lett., 38, 2333-4 (1997).

 

274)     Dowex-1-Supported Rhodium and Platinum Containing Ion Pairs as Selective and Recyclable Catalysts for Various Hydrogen Transfer Processes.  M. Setty-Fichman, Y. Sasson, and J. Blum.  Proc. 213th Amer. Chem. Soc., National Meeting, San Francisco, April, 1997, ORGN  073.

275)     Organoaluminum and Organogallium Complexes as Efficient and Selective Alkylating Agents.  W. Baidossi, J. Blum, M. Frick, D. Gelman, B. Heymer, H. Schumann, S. Schutte and E. Shakh, in "Organic Synthesis via Organometallics" OSM5, G. Helmchen, J. Dibo, D. Flubacher and B. Wiese (Eds), F. Vieweg & Sohn, Braunschweig, 1997, pp. 51-57.

 

276)     H2[Pt3(CO)6]n as Highly Efficient Alkyne Hydration Catalysts.  J. Blum, W. Baidossi and M. Lahav, Proc. 32nd Internat. Conference Coordin. Chem., Santiago de Chile, Aug. 1997, 7O9, p. 110.

 

277)     Immobilized Rhodium and Platinum Containing Ion Pairs Generated from Quaternary Ammonium Salts and the Respective Metal Chlorides, as Selective and Recyclable Catalysts for Various Hydrogen Transfer Processes.  M. Setty-Fichman, Y. Sasson and J. Blum, Proc. 1997 Int. Phase Transfer Catalysis Conference, Nagoya, Sept. 1997, P-11, p. 65.

 

278)     Double Bond Migration, Cyclohexadiene Disproportionation and Alkyne Hydration by Dowex 1-RhCl3 Ion Pair Catalysts.  M. Setty-Fichman, Y. Sasson and J. Blum, J. Mol. Catal. A:  Chem., 126, 27-36 (1997).

 

279)     Palladium Catalyzed Methylation of Aryl and Vinyl Halides by Stabilized Methylaluminum and Methylgallium Complexes.  J. Blum, D. Gelman, W. Baidossi, E. Shakh, A. Rosenfeld, Z. Aizenshtat, B.C. Wassermann, M. Frick, B. Heymer, S. Schutte, S. Wernik and H. Schumann, J. Org. Chem., 62, 8681-8686 (1997).

 

280)     Catalysis by Sol-Gel Entrapped Transition Metal Complexes.  J. Blum, Proc. 1997 Nat. Workshop on Catalysis, Thiruvananthapuram, Dec. 1997, pp. 5-6.

 

281)     Catalysis by Polymer-Supported Ion Pairs. J. Blum, Proc. 1997 Nat. Workshop on Catalysis, Thiruvananthapuram, Dec. 1997, pp. 6-7.

 

282)     New Applications of Some Sol-Gel Entrapped Transition Metal Catalysts.  J. Blum, F. Gelman, A. Rosenfeld, I. Hariton, H. Schumann and D. Avnir.  Proc. 63rd Meeting, Isr. Chem. Soc., Tel Aviv, Feb. 1998, p. 27.

 

283)     Resolution of Four K-Region Arene Imines and Mutagenicity of the Optically Pure Aziridines.  J. Blum, Y. Cohen, S. Levin, A. Katschak and H. Glatt, J. Heterocyclic Chem., 35, 39-43 (1998).

 

284)     Metal Silicates by Molecular Route as Catalysts for Epoxidation of Alkenes with t-Butyl-hydroperoxide.  D. Juwiler, J. Blum and R. Neumann, Chem. Commun., 1123-1124 (1998).

 

285)     Synthesis, Immobilization and Catalytic Activity of Some Silylated Cyclopentadienyl Rhodium(I) Complexes.  H. Schumann, M. Hasan, F. Gelman, D. Avnir and J. Blum, Inorg. Chim. Acta, 280, 21-25 (1998).

 

286)     Kinetic Resolution of Racemic 2,2-Bis(trifluoromethanesulfonyloxy)-1,1-binaphthalene by Palladium Catalyzed Cross-Methylation with Stabilized Dimethylaluminum Reagents.  J. Blum, D. Gelman, Z. Aizenshtat, S. Wernik and H. Schumann.  Tetrahedron Lett., 39, 5611-5614 (1998).

 

287)     Application of Sol-Gel Encapsulated Platinoid Metal Catalysts to Enantioselective Hydrogenation of Double Bonds and to Selective Hydrogenolysis of Aryl Halides.  J. Blum, F. Gelman, A. Rosenfeld, D. Avnir and H. Schumann.  Proc. 9th Inter. Symp. on Relations between Homogeneous and Heterogeneous Catalysis, Southampton, July, 1998, p. C13.

 

288)     Applications of Sol-Gel Encapsulated Transition Metal Catalysts.  J. Blum, D. Avnir and H. Schumann, Chemtech , 29 (2) 32-38 (1999).

 

289)     Palladium-Catalyzed Alkylation of Aryl Halides and Triflates by Stabilized Dialkylaluminum,-gallium and -indium Complexes. J. Blum. Frontiers in Chemistry and Materials Science, 4th Joint Symposium of the Hebrew University of Jerusalem and the Technical University of Berlin, Jerusalem, February, 1999, p. 9.

 

290)     Palladium Catalyzed Cross-Methylation of Aryl Triflate by Intramolecularly Stabilized Dimethylaluminium and -gallium Complexes.  J. Katz, M. Michman and J. Blum, The 64th Meeting, Israel Chemical Society, Ramat-Gan, March, 1999, p. 104.

 

291)     Further Studies on the Hydration of Acetylenes by Platinum-Carbonyl Complexes.  O. Israelsohn, N. Itzhak, K.P.C. Vollhardt and J. Blum. The 64th Meeting, Israel Chemical Society, Ramat-Gan, March, 1999, p. 111.

 

292)     Activation of Aromatic Chlorine Atoms in Palladium Catalyzed Cross-Alkylation of Aryl Chlorides.  O. Berlin, Y. Ben-David, D. Milstein and J. Blum. The 64th Meeting, Israel Chemical Society, Ramat-Gan, March, 1999, p. 119.

 

293)     Metal Silicates by a Molecular Route as Catalysts for the Epoxidation of Alkenes with tert-Butyl Hydroperoxide, D. Juwiler, J. Blum and R. Neumann, The 64th Meeting, Israel Chemical Society, Ramat-Gan, March, 1999, p. 114.

 

294)     DOWEX-1 Supported PtCl4 Ion Pair as a Recyclable Hydrogenation Catalyst.  M. Setty-Fichman, K. Kupferman, V. Batz, C. Rottman, Y. Sasson and J. Blum. J. Mol. Catal. A.: Chem., 144, 159-163 (1999).

 

295)     Sol-Gel Entrapped Heteronuclear Transition Metal Catalysts.  J. Blum, F. Gelman, R. Abu-Reziq, I. Miloslavski, H. Schumann and D. Avnir. (a) Proc. 10th IUPAC Symposium on Organo-Metallic Chemistry Directed Towards Organic Synthesis, Versailles (France), July 1999, SL-2; (b)  Polyhedron, 19, 509-512 (2000).

 

296)     Synthesis of Nucleoside Adducts of Highly Mutagenic Polycyclic Aromatic Imines.  Y. Shalom, R.G. Harvey and J. Blum, Tetrahedron, 55, 10231-10242 (1999).

 

297)     Hydrogenation and Dehalogenation of Aryl Chlorides and Fluorides by Sol-Gel Entrapped RhCl3-Aliquat 336 Ion Pair Catalyst.  J. Blum, A. Rosenfeld, F. Gelman, H. Schumann and D. Avnir.  J. Mol. Catal. A.: Chem., 146, 117-122 (1999).

 

298)     Sol-Gel Entrapped Chiral Rhodium and Ruthenium Complexes as Recyclable Catalysts for the Hydrogenation of Itaconic Acid.  F. Gelman, D. Avnir, H. Schumann and J. Blum.  J. Mol. Catal. A.: Chem., 146, 123-128 (1999).

 

299)    New Development in Reactive Sol-Gel Materials.  D. Avnir, J. Blum, H. Frenkel, F. Gelman and C. Rottman, Proc. 10th Internat. Workshop on Glasses, Ceramics, Hybrids and Nanocomposites from Gels, Yokohama (Japan), Sept. 1999, p. 1.

 

 

300)     Advances in Alkylation and Cross-Coupling Processes by Intramolecularly Stabilized Dialkylaluminum, -Gallium and –Indium Complexes.  J. Blum, Y. Ben-David, O. Berlin, D. Gelman, N. Jaber, D. Milstein, H. Schumann, S. Schutte and B.C. Wassermann, Proc. 65th Meeting, Isr. Chem. Soc., Beer-Sheva, Feb. 2000, p. 59.

 

301)     Palladium-Catalyzed Cross-Methylation of Aryl Chlorides by Stabilized Dimethyl-aluminum and -Gallium Reagents.  J. Blum, O. Berlin, D. Milstein, Y. Ben-David, B.C. Wassermann, S. Schutte and H. Schumann, Synthesis, 571-575 (2000).

 

302)     New Developments in Catalytic Alkylation and Cross-Coupling Reactions by Group 13-Metal Complexes.  J. Blum, Proc. 23rd Annual Meeting of the Chemical Society of Brazil, Pocos de Caldas, MG, Brazil, May 2000, CT-043.

 

303)     Reactive Functional Porous Sol-Gel Materials.  D. Avnir, J. Blum, H. Frenkel, F. Gelman, C. Rottman and L. Sarussi, Proc. Internat. Workshop, on Characterization of Porous Materials (invited lecture), Princeton, N.J.,  June 19-21, 2000.

 

304)     Palladium and Nickel-Catalyzed Cross-Coupling of Aryl Chlorides by Stabilized Dialkylaluminum, -Gallium and –Indium.  D. Gelman, O. Berlin, N. Jaber, Y. Ben-David, D. Milstein, H. Schumann and J. Blum.  Proc. 34th Internat. Conference Coordin. Chem., Edinburgh, UK, July 2000, oral presentation II II.

 

305)     Sol-Gel Entrapped TEMPO for the Selective Oxidation of Methyl-D-glucopyranoside.  R. Ciriminna, J. Blum, D. Avnir and M. Pagliaro, Chem. Commun., 1441-1442 (2000).

 

306)     Further Studies on Polycyclic Arene Sulfides.  Preparation and Mutagenic Activity of 9,10,10a,11a-tetrahydrotriphenyleno[1,2,b]fluorene and 1a,2,3,11b-Tetrahydroacenaphtho-[1,2:6,7]naphth[1,2-b]thiirene.  J. Blum, V. Kogan and H. Glatt, J. Heterocyclic Chem., 37, 1109-1112 (2000).

 

307)     Dichlorobis(triphenylphosphine)nickel-catalyzed Cross-Coupling of Aryl Chlorides with Intramolecularly Stabilized Group 13-Metal Alkylating Regents.  D. Gelman, H. Schumann and J. Blum.  Tetrahedron Lett., 41, 7555-7558 (2000).

 

308)    Doped Sol-Gel Materials as Heterogeneous Reagents for Organic Synthesis.  L. Sarussi, J. Blum and D. Avnir, J. Sol-Gel Sci. Tech., 19, 17-22 (2000).

 

309)     One-pot Reactions with Opposing Sol-Gel Entrapped Reagents: A Base/Metal Complex System.  F. Gelman, J. Blum and D. Avnir, J. Am. Chem. Soc., 122, 11999-12000 (2000).

 

310)     Palladium-Catalyzed Cross-Methylation of Aryl Triflates by Intramolecularly Stabilized Dialkylaluminum, -Gallium and –Indium Reagents.  J. Blum, J.A. Katz, N. Jaber, M. Michman, H. Schumann, S. Schutte, J. Kaufmann and B.C. Wassermann, J. Mol. Catal. A: Chem., 165, 97-102 (2001).

 

311)     Comparison between PdCl2(PPh3)2- and NiCl2(PPh3)2-Catalyzed Cross-Coup;ling of Aryl Halides by Intramolecularly Stabilized Dialkylaluminum Reagents.  D. Gelman, G. Hhne, H. Schumann and J. Blum, Synthesis, 591-594 (2001).

 

312)     Sol-Gel Entrapped Rh2Co2(CO)12: A Catalyst Precursor for Efficient Arene Hydrogenation.  F. Gelman, D. Avnir, H. Schumann and J. Blum, J. Mol. Catal. A: Chem., 171, 191-194 (2001).

313)     Matrix Protection Against Catalyst Poisoning and Opposing Reagents.  J. Blum, F. Gelman, H. Schumann and D. Avnir, 11th IUPAC Symposium on Organometallic Chemistry Directed towards Organic Synthesis, Taipei, Taiwan, July 2001, SL-24 (P053).

 

314)     Highly Selective Nickel-Catalyzed Cross-Coupling of Aryl Chlorides with Intramolecularly Stabilized Dialkylaluminum and –indium Reagents.  D. Gelman, H. Schumann and J. Blum.  Post OMCOS-11 Symposium on Thirty Years of the Cross-Coupling Reaction, Kyoto, Japan, July 2001, SOP-02 (P-051).

 

315)     Acids and Bases in One Pot while Avoiding Their Mutual Destruction.  F. Gelman, J. Blum and D. Avnir, Angew. Chem.  113, 3759-3761 (2001); Angew. Chem. Int. Ed., 40, 3647-3649 (2001).

 

316)     Progress in the Design and Applications of Ormosils.  J. Blum, F. Gelman, S. Fireman-Shoresh, H. Frenkel, H. Sertchook and D. Avnir.  11th Internat. Workshop on Glasses, Ceramics, Hybrids and Nanocomposites from Gels, Padova, Italy, Sept. 2001, I 11, pp 8-9.

 

317)     Reactive Ceramic Nanocomposites with Organic and Bio-organic Phases. D. Avnir, J. Blum and O. Lev in The Encyclopedia of Materials: Science and Technology, K.H.J. Buschow, M.C. Flemings, E.J. Kramer, R.W. Cahn, B. Ilschner, S. Mahajan (Eds.), Elsevier Science Ltd., Amsterdam, 2001, pp. 8040-8049.

 

318)     Selective Palladium-Catalyzed Cross-Methylation of Halo- and Pseudohaloarenes with Intramolecularly Stabilized Methylindium Reagents.  N. Jaber and J. Blum.  67th Meeting Isr. Chem. Soc., Jerusalem, Jan. 2002, p. 207.

 

319)     Green Chemistry.  Complete Hydrodechlorination of Chlorinated Environmental Pollutants by a Sol-Gel-Entrapped Rh-Pd Mixed-Metal Catalyst.  A. Ghattas, R. Abu-Reziq, D. Avnir and J. Blum. 67th Meeting Isr. Chem. Soc., Jerusalem, Jan. 2002, p. 208.

 

320)     Sodium Tetraalkynyl Aluminates as Efficient Alkynylating Reagents for Palladium-Catalyzed Cross-Coupling and Lanthanide Promoted Carbonyl Addition Processes.  D. Gelman, D. Tsvelikhovsky, G.A. Molander and J. Blum. 67th Meeting Isr. Chem. Soc., Jerusalem, Jan. 2002, p. 209.

 

321)     A Sol-Gel Entrapped Combined Pd-Rh System.  A Super Catalyst for C=O and Aromatic C-C Bond Hydrogenation.  R. Abu-Reziq, D. Avnir and J. Blum, 67th Meeting Isr. Chem. Soc., Jerusalem, Jan. 2002, p. 210.

 

322)     Cross-Alkylation of Haloarenes with Intramolecularly Stabilized Group-13 Metal Alkylating Reagents in the Presence of a Fe-Pd Mixed Metal Catalyst.  M. Kofman, D. Gelman and J. Blum. 67th Meeting Isr. Chem. Soc., Jerusalem, Jan. 2002, p. 211.

 

323)     Further Studies on Hydration of Alkynes by the PtCl4-CO Catalyst.  O. Israelsohn, K.P.C. Vollhardt and J. Blum, J. Mol. Catal. A: Chem., 184, 1-10 (2002).

 

324)     Synthesis, Structure and Catalytic Activity of Some New Chiral 2-Menthylindenyl and 2-Menthyl-4,7-dimethylindenyl Rhodium Complexes.  H. Schumann, O. Stenzel, S. Dechert, F. Girgsides, J. Blum, D. Gelman and R.L. Halterman.  Eur. J. Inorg. Chem, 211-219 (2002).

 

 

325)     2,2-Bipyridine, 2-(2-Oxazolyl)pyridine and 2,2-Bisoxazole Derived Nickel(0) Complexes as Selective Catalysts for Cross-Coupling of Aryl Chlorides by Intramolecularly Stabilized Dialkylaluminum Reagents.  D. Gelman, S. Dechert, H. Schumann and J. Blum, Inorg. Chim. Acta, 334, 149-158 (2002).

 

326)     Entrapment of a Metallic Palladium and a Rhodium(I) Complex in a Silica Sol-Gel Matrix.  Formation of a Highly Active Recyclable Arene Hydrogenation Catalyst.  R. Abu-Reziq, D. Avnir, I. Miloslavski, H. Schumann and J. Blum.  J. Mol. Catal. A: Chem., 185, 179-185 (2002).

 

327)     Palladium-Catalyzed Cross-Methylation of Haloarenes Having Active Hydrogen Atoms by Intramolecularly Stabilized Dimethylindium and Dimethylaluminum Reagents.  N. Jaber, D. Gelman, H. Schumann, S. Dechert and J. Blum, Eur. J. Org. Chem., 1628-1633 (2002).

 

328)       Synthesis and Characterization of Intramolecularly Stabilized Chiral Dimethylindium Alkoxides and their Use as Cross-coupling Reagents. H. Schumann, J. Kaufmann, B.C. Wassermann, F. Girgsdies, N. Jaber and J. Blum,  Z. Anorg. Allg. Chem., 628, 971-978 (2002).

 

329)     Intramolecularly Stabilized Dimethylindium Complexes as Efficient and Selective Cross-methylation Reagents.  N. Jaber, J. Kaufmann, H. Schumann and J. Blum, 20th Internat. Conference Organomet. Chem,  Corfu, July 2002, p. 159.

 

330)     Catalytic Hydrogenation of Aromatic Ketones by a Sol-Gel Entrapped Combined Pd-[Rh(cod)Cl]2 Catalyst.  R. Abu-Reziq, D. Avnir and J. Blum, J. Mol. Catal. A: Chem.,  187, 277-281 (2002).

 

331)       Palladium-Catalyzed Cross-Alkynylation of Aryl Bromides by Sodium Tetraalkynyl-aluminates.  D. Gelman, D. Tsvelikhovsky, G.A. Molander and J. Blum, J. Org. Chem., 67, 6287-6290 (2002).

 

332)       A Three-Phase Emulsion/Solid Heterogenization Method for Transport and Catalysis.  R. Abu-Reziq, D. Avnir  and J. Blum, Angew. Chem., 114, 4311-4313; Angew. Chem., Int. Ed., 41, 4132-4134 (2002).

 

333)    One-Pot Sequences of Reactions with Sol-Gel Entrapped Opposing Reagents: An Enzyme and Metal-Complex Catalysts.  F. Gelman, J. Blum and D. Avnir, J. Am. Chem. Soc, 124, 14460-14463 (2002).

 

334)    One-Pot Reactions with Sol-Gel Entrapped Catalysts, Acids and Bases. F. Gelman, J. Blum, H. Schumann and D. Avnir, J. Sol-Gel Sci. Tech., 26, 43-46 (2003).

 

335)    One-Pot Sequences of Reactions with Sol-Gel Entrapped Opposing Reagents: Oxidations and Catalytic Reductions.  F. Gelman, J. Blum and D. Avnir, New J. Chem., 27, 205-207 (2003).

 

336)    Cross-Coupling of Aryl Halides and Triflates with Intramolecularly Stabilized Group 13-Metal Alkylating Reagents in the Presence of Mixed-Metal Catalysts.  M. Shenglof, D. Gelman, B. Heymer, H. Schumann, G.A. Molander and J. Blum, Synthesis, 302-306 (2003).

 

337)    Exhaustive Hydrodechlorination of Chlorinated Aromatic Environmental Pollutants to Alicyclic Compounds.  A. Ghattas, R. Abu-Reziq, D. Avnir and J. Blum, Green Chemistry, 5, 40-43 (2003).

 

338)    Palladium-Catalyzed Cross-Methylation of Bromoheterocycles with Intramolecularly Stabilized Dimethyl Indium Reagents.  N. Jaber, H. Schumann and J. Blum, J. Heterocyclic Chem., 40, 565-567 (2003).

 

339)    Lanthanide Assisted Cross-Coupling of Aryl Bromides with Triethylaluminum.  M. Shenglof, D. Gelman, G.A. Molander and J. Blum, Tetrahedron Lett., 44, 8593-8595 (2003).

 

340)    One-Pot Sequences of Reactions with Sol-Gel Entrapped Opposing Catalysts and Reagents.  J. Blum, D. Avnir, F. Gelman and K. Hamza, 69th Meeting Isr. Chem. Soc., Tel Aviv, Feb. 2004, p. 66.

 

341)    Three-Phase Emulsion/Sol-Gel System for Aqueous Catalysis with Hydrophobic Materials.  R. Abu-Reziq, D. Avnir and J. Blum, 69th Meeting Isr. Chem. Soc., Tel Aviv, Feb. 2004, p. 112.

 

342)    Conversion of Inactive Ruthenium, Osmium and Rhodium Carbonyls into Active Hydrogenation Catalysts by their Entrapment within Alumina Sol-Gel Matrices.  N. Eliau and J. Blum, 69th Meeting Isr. Chem. Soc., Tel Aviv, Feb. 2004, p. 148.

 

343)    A One-Pot Heck Reaction by Sol-Gel Entrapped PdCl2(PPh3)2 Coupled with a Photocyclization Process.  K. Hamza, R. Abu-Reziq, D. Avnir and J. Blum, 69th Meeting Isr. Chem. Soc., Tel Aviv, Feb. 2004, p. 171.

 

344)    Remote Control Synergism between Sol-Gel Entrapped [Rh(cod)Cl]2 and Na[HRu3(CO)11] in Catalytic Hydrogenation and Hydroformylation Reactions.  L. Penn, R. Abu-Reziq and J. Blum, 69th Meeting Isr. Chem. Soc., Tel Aviv, Feb. 2004, p. 216.

 

345)    The Effect of Lanthanide Salts on Palladium-Catalyzed Cross-Ethylation of Bromoarenes with Triethylaluminum.  M. Shenglof, D. Gelman, G. Molander and J. Blum, 69th Meeting Isr. Chem. Soc., Tel Aviv, Feb. 2004, p. 250.

 

346)    Lanthanide-Catalyzed Alkylation of Schiff Bases and Nitriles.  D. Tsvelikhovsky, D. Gelman, G. Molander and J. Blum, 69th Meeting Isr. Chem. Soc., Tel Aviv, Feb. 2004, p. 270.

 

347)    Three-Phase Microemulsion/Sol-Gel System for Aqueous Catalysis with Hydrophobic Chemicals.  R. Abu-Reziq, J. Blum and D. Avnir, Chem. Eur. J., 10, 958-962 (2004).

 

348)    Heck Vinylation of Aryl Iodides by a Silica Entrapped Pd(II) Catalyst and Its Combination with a Photocyclization Process.  K. Hamza, R. Abu-Reziq, D. Avnir and J. Blum, Org. Lett. 6, 925-927 (2004).

 

349)    Lanthanide-Promoted Ethylation of Schiff Bases by Triethylaluminum.  D. Tsvelikhovsky, D. Gelman, G.A. Molander and J. Blum, Org. Lett.,  6, 1995-1997 (2004).

 

350)    Catalysis and Reactivity with Sol-Gel Entrapped Organic and Organometallic Chemicals.  J. Blum and D. Avnir in: Handbook of Sol-Gel Science and Technology, S. Sakka (Ed.) Kluwer Scientific Publishers, Boston, Vol. 3, Chapter 24. pp. 507-526, 2005.

 

351)    Hydrodechlorination of Chlorophenols by a Sol-Gel Entrapped Combined Palladium-Rhodium Catalyst.  T.T. Bovkum, M. Rona, Y. Sasson and J. Blum, 70th Meeting Isr. Chem. Soc., Tel Aviv, Feb. 2005, p. 151.

 

352)    Cross-Coupling of Intramolecularly Stabilized Dialkylindium Reagents with Aryl Bromides, Iodides and Triflates in the Presence of a Recyclable Palladium Catalyst.  A. Talhami and J. Blum, 70th Meeting Isr. Chem. Soc., Tel Aviv, Feb. 2005, p. 153.

 

353)    Sol-Gel Entrapped Pyridinium Hydrobromide Perbromide as Bromination Agent and Its Application to One-Pot Bromination-Dehydrobromination Reactions.  K. Hamza and J. Blum, 70th Meeting Isr. Chem. Soc., Tel Aviv, Feb. 2005, p. 155.

 

354)    Suzuki, Kumada and Stille Cross-Coupling Processes Catalyzed by Sol-Gel Entrapped PdCl2(PPh3)2.  L. Penn and J. Blum, 70th Meeting Isr. Chem. Soc., Tel Aviv, Feb. 2005, p. 157.

 

355)    Cross-Coupling of Aryl Halides Catalyzed by Palladium-Molybdenum and by Palladium-Tungsten Mixed-Metal Catalysts.  M. Shenglof, M. Pirkes, G.A. Molander and J. Blum, 70th Meeting Isr. Chem. Soc., Tel Aviv, Feb. 2005, p. 159.

 

356)    Hydrodefunctionalization of Aromatic Chloro-, Nitro- and Amino-Derivatives of Environmental Pollutants by a Recyclable Sol-Gel Entrapped Palladium-Rhodium Catalyst.  T.T. Bovkun,Y. Sasson and J. Blum, The 12th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis, Florence, Italy, 18th-22nd July, 2005, OC-3, p. 45.

 

357)    Three-Phase Microemulsion/Sol-Gel System for Aqueous Catalytic Hydroformylation of Hydrophobic Alkenes.  R. Abu-Reziq, D. Avnir and J. Blum, Eur. J. Org. Chem., 3640-2642 (2005).

 

358)    Activation of Metal-Carbonyl Clusters by their Encapsulation within Alumina Sol-Gel Matrices.  N. Eliau, D. Avnir, M.S. Eisen and J. Blum, J. Sol-Gel Sci. Tech., 35, 157-167 (2005).

 

359)    Conversion of Chlorophenols into Cyclohexane by a Recyclable Pd-Rh Catalyst.  T.T. Bovkun, Y. Sasson and J. Blum, J. Mol. Catal. A: Chem., 242, 68-73 (2005).

 

360)    Cross-Coupling of Aryl Halides and Triflates with Group 13-Metal Alkylating Reagents by Palladium-Molybdenum and Palladium-Tungsten Mixed-Metal Catalysts.  M. Shenglof, G.A. Molander and J. Blum, Synthesis, 111-114 (2006).

 

361)    Sol-Gel Entrapped Pyridinium Hydrobromide Perbromide as a Recyclable Bromination Agent.  Its Application to a One-Pot Bromination and Dehydrobromination Process.  Y. Levin, K. Hamza, R. Abu-Reziq and J. Blum, Eur. J. Org. Chem., 1396-1399 (2006).

 

362)    Cerium(IV) Promoted Ethylation of Schiff Bases by Triethylaluminum.  D. Tsvelikhovsky, H. Schumann and J. Blum, Synthesis, 1819-1822 (2006).

 

363)    Sol-Gel Entrapped Dichlorobis(triphenylphosphine)palladium as an Efficient Recyclable Catalyst for the Cross-Coupling of Aryl Halides with Indium- and Related Alkylating Reagents. A. Talhami, L. Penn, N. Jaber, K. Hamza and J. Blum.  Appl. Catal. A: General, 312, 115-119 (2006).

364)    One-pot Combination of the Wittig Olefination with Oxidation, Hydrogenation, Bromination and Photocyclization Reactions.  K. Hamza and J. Blum, Tetrahedron Lett., 48, 293-295 (2007).

 

365)    Two New Applications of Sol-Gel Technology to Organic Synthesis: Catalysis with Hydrophobic Substrates in Aqueous Microemulsions and Hydrodenitrogenation of Carcinogenic Polycylic Nitroarenes.  D. Tsvelikhovsky, T.T. Bovkun, R. Abu-Reziq, Y. Sasson, D. Avnir and J. Blum, 72nd Meeting Isr. Chem. Soc., Tel-Aviv, Feb. 2007, S1b3, abstr. 148.

 

366)    Selective Hydroformylation of Vinylarenes Catalyzed by a Rhodium Complex Entrapped within a Silica Sol-Gel Matrix Modified with an Ionic Liquid. K. Hamza and J. Blum. 72nd Meeting Isr. Chem. Soc., Tel-Aviv, Feb. 2007, abstr. 229.

 

367)    Liquid-Phase Hydrogenation and Hydrodenitrogenation of Aromatic Nitrogen-Containing Environmental Pollutants.  T. T. Bovkun, M. Grayevsky, Y. Sasson and J. Blum, J. Mol. Catal. A: Chem.,  270, 171-176 (2007).

 

368)    Highly Selective Hydroformylation of Vinylarenes to Branched Aldehydes by [Rh(cod)Cl]2 Entrapped in Ionic Liquid Modified Silica Sol-Gel.  K. Hamza and J. Blum.  Eur. J. Org. Chem., 4706-4710 (2007).

 

369)    One-Pot Multi-Step Transformation of Vinylarenes into Dinitriles by a Rhodium Catalyst Entrapped Within an Ionic Liquid Modified Sol-Gel Matrix.  K. Hamza and J. Blum, 73rd Meeting Isr. Chem. Soc., Jerusalem, Feb. 2008, p. 228.

 

370)    Three Phase Microemulsion/Sol-Gel System for Aqueous C-C Coupling of Hydrophobic Substrates.  D. Tsvelikhovsky and J. Blum, Eur. J. Org. Chem., 2417-2422  (2008).

 

371)    Hydrogenation of Arenes, Alkenes and Alkynes Catalyzed by a Sol-Gel Entrapped Mixture of [Rh(cod)Cl]2 and Na[HRu3(CO)11].  R. Abu-Reziq, M. Shenglof, L. Penn, T. Cohen and J. Blum. J. Mol. Catal. A: Chem. 290, 30-34 (2008).

 

372)    Forcing a cis-Product by Matrix Imprinting: Heck Reaction Catalyzed by Pd(OAc)2 Entrapped within cis-Imprinted Sol-Gel Derived Silicates, D. Tsvelikhovsky, D. Pessing, D. Avnir, J. Blum, Adv. Synth. Catal. 350, 2856-2858 (2008).

 

373)    On the Involvement of Pd Nanoparticles in the Heck and Suzuki Reactions.  D. Tsvelikhovsky, I. Popov, V. Gutkin, A. Rozin, A. Shvartsman and J. Blum, Eur. J. Org. Chem., 98-102 (2009).

 

374)    Application of Sol-Gel Entrapped Palladium Carboxylates to Stereoselective Nanoparticle-Assisted and to Nanoparticle-Free Heck Coupling.  D. Tsvelikhovsky, A. Rozin Ben-Baruch, D. Avnir and J. Blum,  74th Meeting, Isr. Chem. Soc., Tel Aviv, Feb. 2009, abstr. P2-63.

 

375)    One-Pot-Selective Hydroformylation Condensation and Hydrogenation Processes by a Sol-Gel Entrapped Rhodium Complex, an Immobilized Base and an Ionic Liquid. K. Hamza, H. Schumann and J. Blum.  Eur. J. Org. Chem., 1502-1505 (2009).

 

376)    Liquid Phase Hydrodechlorination of Some Chlorinated Aromatic Nitrogen-Containing Heterocyclics. K. Omari-Qadry, K. Hamza, Y. Sasson, J. Blum, J. Mol. Catal. A.: Chem., in press.